A dinuclear copper complex: bis­(μ-4-amino­benzoato)bis­[aqua(1,10-phenanthroline)copper(II)] dichloride bis(4-amino­benzoic acid) dihydrate

The title complex, [Cu(2)(C(7)H(6)NO(2))(2)(C(12)H(8)N(2))(2)(H(2)O)(2)]·2C(7)H(7)NO(2)·2H(2)O, consists of a dinuclear [Cu(2)(C(7)H(6)NO(2))(2)(C(12)H(8)N(2))(2)(H(2)O)(2)](2+) cation, two Cl(−) anions, two 4-amino­benzoic acid mol­ecules and two disordered water mol­ecules (site occupancy factors...

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Autores principales: Huang, Miao-Ling, Xie, Qing-Fan, Xian, Jing-Chun, Chen, Yan-Min, Zhou, Zi-Qiao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961994/
https://www.ncbi.nlm.nih.gov/pubmed/21203064
http://dx.doi.org/10.1107/S1600536808023647
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author Huang, Miao-Ling
Xie, Qing-Fan
Xian, Jing-Chun
Chen, Yan-Min
Zhou, Zi-Qiao
author_facet Huang, Miao-Ling
Xie, Qing-Fan
Xian, Jing-Chun
Chen, Yan-Min
Zhou, Zi-Qiao
author_sort Huang, Miao-Ling
collection PubMed
description The title complex, [Cu(2)(C(7)H(6)NO(2))(2)(C(12)H(8)N(2))(2)(H(2)O)(2)]·2C(7)H(7)NO(2)·2H(2)O, consists of a dinuclear [Cu(2)(C(7)H(6)NO(2))(2)(C(12)H(8)N(2))(2)(H(2)O)(2)](2+) cation, two Cl(−) anions, two 4-amino­benzoic acid mol­ecules and two disordered water mol­ecules (site occupancy factors 0.5). The Cu(II) ion adopts a distorted square-pyramidal geometry formed by two N atoms from the 1,10-phenanthroline ligand and two O atoms of the two 4-amino­benzoic acid ligands and one water O atom. The Cu⋯Cu separation is 3.109 (2) Å. A twofold axis passes through the mid-point of the Cu⋯Cu vector.
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spelling pubmed-29619942010-12-30 A dinuclear copper complex: bis­(μ-4-amino­benzoato)bis­[aqua(1,10-phenanthroline)copper(II)] dichloride bis(4-amino­benzoic acid) dihydrate Huang, Miao-Ling Xie, Qing-Fan Xian, Jing-Chun Chen, Yan-Min Zhou, Zi-Qiao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Cu(2)(C(7)H(6)NO(2))(2)(C(12)H(8)N(2))(2)(H(2)O)(2)]·2C(7)H(7)NO(2)·2H(2)O, consists of a dinuclear [Cu(2)(C(7)H(6)NO(2))(2)(C(12)H(8)N(2))(2)(H(2)O)(2)](2+) cation, two Cl(−) anions, two 4-amino­benzoic acid mol­ecules and two disordered water mol­ecules (site occupancy factors 0.5). The Cu(II) ion adopts a distorted square-pyramidal geometry formed by two N atoms from the 1,10-phenanthroline ligand and two O atoms of the two 4-amino­benzoic acid ligands and one water O atom. The Cu⋯Cu separation is 3.109 (2) Å. A twofold axis passes through the mid-point of the Cu⋯Cu vector. International Union of Crystallography 2008-07-31 /pmc/articles/PMC2961994/ /pubmed/21203064 http://dx.doi.org/10.1107/S1600536808023647 Text en © Huang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Huang, Miao-Ling
Xie, Qing-Fan
Xian, Jing-Chun
Chen, Yan-Min
Zhou, Zi-Qiao
A dinuclear copper complex: bis­(μ-4-amino­benzoato)bis­[aqua(1,10-phenanthroline)copper(II)] dichloride bis(4-amino­benzoic acid) dihydrate
title A dinuclear copper complex: bis­(μ-4-amino­benzoato)bis­[aqua(1,10-phenanthroline)copper(II)] dichloride bis(4-amino­benzoic acid) dihydrate
title_full A dinuclear copper complex: bis­(μ-4-amino­benzoato)bis­[aqua(1,10-phenanthroline)copper(II)] dichloride bis(4-amino­benzoic acid) dihydrate
title_fullStr A dinuclear copper complex: bis­(μ-4-amino­benzoato)bis­[aqua(1,10-phenanthroline)copper(II)] dichloride bis(4-amino­benzoic acid) dihydrate
title_full_unstemmed A dinuclear copper complex: bis­(μ-4-amino­benzoato)bis­[aqua(1,10-phenanthroline)copper(II)] dichloride bis(4-amino­benzoic acid) dihydrate
title_short A dinuclear copper complex: bis­(μ-4-amino­benzoato)bis­[aqua(1,10-phenanthroline)copper(II)] dichloride bis(4-amino­benzoic acid) dihydrate
title_sort dinuclear copper complex: bis­(μ-4-amino­benzoato)bis­[aqua(1,10-phenanthroline)copper(ii)] dichloride bis(4-amino­benzoic acid) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961994/
https://www.ncbi.nlm.nih.gov/pubmed/21203064
http://dx.doi.org/10.1107/S1600536808023647
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