[N′-(1,3-Dioxoindan-2-yl­idene)-2-oxido­benzohydrazidato-κ(3) O (2),N,O]tripyridine­nickel(II) pyridine solvate

In the title compound, [Ni(C(16)H(8)N(2)O(4))(C(5)H(5)N)(3)]·C(5)H(5)N, the Ni(II) atom is six-coordinated by two O atoms and one N atom from the Schiff base ligand and by three N atoms from three pyridine mol­ecules, forming a distorted octa­hedral geometry. The Ni—O(phenolate) bond [1.9750 (16) Å]...

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Autores principales: Liu, Wei-Sheng, Wu, Da-Xiang, Chen, Jia-Yu, Wang, Hui-Juan, Tang, Xiao-Liang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961996/
https://www.ncbi.nlm.nih.gov/pubmed/21203066
http://dx.doi.org/10.1107/S1600536808023489
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author Liu, Wei-Sheng
Wu, Da-Xiang
Chen, Jia-Yu
Wang, Hui-Juan
Tang, Xiao-Liang
author_facet Liu, Wei-Sheng
Wu, Da-Xiang
Chen, Jia-Yu
Wang, Hui-Juan
Tang, Xiao-Liang
author_sort Liu, Wei-Sheng
collection PubMed
description In the title compound, [Ni(C(16)H(8)N(2)O(4))(C(5)H(5)N)(3)]·C(5)H(5)N, the Ni(II) atom is six-coordinated by two O atoms and one N atom from the Schiff base ligand and by three N atoms from three pyridine mol­ecules, forming a distorted octa­hedral geometry. The Ni—O(phenolate) bond [1.9750 (16) Å] is shorter than the Ni—O(carbon­yl) bond [2.0840 (16) Å] and the Ni—N bonds (mean 2.120 Å).
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spelling pubmed-29619962010-12-30 [N′-(1,3-Dioxoindan-2-yl­idene)-2-oxido­benzohydrazidato-κ(3) O (2),N,O]tripyridine­nickel(II) pyridine solvate Liu, Wei-Sheng Wu, Da-Xiang Chen, Jia-Yu Wang, Hui-Juan Tang, Xiao-Liang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(16)H(8)N(2)O(4))(C(5)H(5)N)(3)]·C(5)H(5)N, the Ni(II) atom is six-coordinated by two O atoms and one N atom from the Schiff base ligand and by three N atoms from three pyridine mol­ecules, forming a distorted octa­hedral geometry. The Ni—O(phenolate) bond [1.9750 (16) Å] is shorter than the Ni—O(carbon­yl) bond [2.0840 (16) Å] and the Ni—N bonds (mean 2.120 Å). International Union of Crystallography 2008-07-31 /pmc/articles/PMC2961996/ /pubmed/21203066 http://dx.doi.org/10.1107/S1600536808023489 Text en © Liu et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Wei-Sheng
Wu, Da-Xiang
Chen, Jia-Yu
Wang, Hui-Juan
Tang, Xiao-Liang
[N′-(1,3-Dioxoindan-2-yl­idene)-2-oxido­benzohydrazidato-κ(3) O (2),N,O]tripyridine­nickel(II) pyridine solvate
title [N′-(1,3-Dioxoindan-2-yl­idene)-2-oxido­benzohydrazidato-κ(3) O (2),N,O]tripyridine­nickel(II) pyridine solvate
title_full [N′-(1,3-Dioxoindan-2-yl­idene)-2-oxido­benzohydrazidato-κ(3) O (2),N,O]tripyridine­nickel(II) pyridine solvate
title_fullStr [N′-(1,3-Dioxoindan-2-yl­idene)-2-oxido­benzohydrazidato-κ(3) O (2),N,O]tripyridine­nickel(II) pyridine solvate
title_full_unstemmed [N′-(1,3-Dioxoindan-2-yl­idene)-2-oxido­benzohydrazidato-κ(3) O (2),N,O]tripyridine­nickel(II) pyridine solvate
title_short [N′-(1,3-Dioxoindan-2-yl­idene)-2-oxido­benzohydrazidato-κ(3) O (2),N,O]tripyridine­nickel(II) pyridine solvate
title_sort [n′-(1,3-dioxoindan-2-yl­idene)-2-oxido­benzohydrazidato-κ(3) o (2),n,o]tripyridine­nickel(ii) pyridine solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961996/
https://www.ncbi.nlm.nih.gov/pubmed/21203066
http://dx.doi.org/10.1107/S1600536808023489
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