Monoclinic polymorph of trans-tetra­aquabis­[(4-pyridylsulfanyl)­acetato-κN]cobalt(II)

The crystal structure of the title compound, [Co(C(7)H(6)NO(2)S)(2)(H(2)O)(4)], is a polymorph of the structure first reported by Du, Zhao & Wang [(2004). Dalton Trans, pp. 2065–2072]. The asymmetric unit of the title compound contains one half-mol­ecule; the Co(II) atom lies on an inversion cen...

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Autores principales: Mikloš, Dušan, Miklovič, Jozef, Moncol, Jan, Segľa, Peter, Koman, Marian
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961997/
https://www.ncbi.nlm.nih.gov/pubmed/21203067
http://dx.doi.org/10.1107/S1600536808023593
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author Mikloš, Dušan
Miklovič, Jozef
Moncol, Jan
Segľa, Peter
Koman, Marian
author_facet Mikloš, Dušan
Miklovič, Jozef
Moncol, Jan
Segľa, Peter
Koman, Marian
author_sort Mikloš, Dušan
collection PubMed
description The crystal structure of the title compound, [Co(C(7)H(6)NO(2)S)(2)(H(2)O)(4)], is a polymorph of the structure first reported by Du, Zhao & Wang [(2004). Dalton Trans, pp. 2065–2072]. The asymmetric unit of the title compound contains one half-mol­ecule; the Co(II) atom lies on an inversion centre in a distorted octa­hedral geometry coordinated by two N atoms of the pyridine rings of the 4-pyridylthio­acetate anions and four O atoms of water mol­ecules. In the crystal structure, inter­molecular O—H⋯O hydrogen bonds link the mol­ecules, forming a three-dimensional network.
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spelling pubmed-29619972010-12-30 Monoclinic polymorph of trans-tetra­aquabis­[(4-pyridylsulfanyl)­acetato-κN]cobalt(II) Mikloš, Dušan Miklovič, Jozef Moncol, Jan Segľa, Peter Koman, Marian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the title compound, [Co(C(7)H(6)NO(2)S)(2)(H(2)O)(4)], is a polymorph of the structure first reported by Du, Zhao & Wang [(2004). Dalton Trans, pp. 2065–2072]. The asymmetric unit of the title compound contains one half-mol­ecule; the Co(II) atom lies on an inversion centre in a distorted octa­hedral geometry coordinated by two N atoms of the pyridine rings of the 4-pyridylthio­acetate anions and four O atoms of water mol­ecules. In the crystal structure, inter­molecular O—H⋯O hydrogen bonds link the mol­ecules, forming a three-dimensional network. International Union of Crystallography 2008-07-31 /pmc/articles/PMC2961997/ /pubmed/21203067 http://dx.doi.org/10.1107/S1600536808023593 Text en © Mikloš et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Mikloš, Dušan
Miklovič, Jozef
Moncol, Jan
Segľa, Peter
Koman, Marian
Monoclinic polymorph of trans-tetra­aquabis­[(4-pyridylsulfanyl)­acetato-κN]cobalt(II)
title Monoclinic polymorph of trans-tetra­aquabis­[(4-pyridylsulfanyl)­acetato-κN]cobalt(II)
title_full Monoclinic polymorph of trans-tetra­aquabis­[(4-pyridylsulfanyl)­acetato-κN]cobalt(II)
title_fullStr Monoclinic polymorph of trans-tetra­aquabis­[(4-pyridylsulfanyl)­acetato-κN]cobalt(II)
title_full_unstemmed Monoclinic polymorph of trans-tetra­aquabis­[(4-pyridylsulfanyl)­acetato-κN]cobalt(II)
title_short Monoclinic polymorph of trans-tetra­aquabis­[(4-pyridylsulfanyl)­acetato-κN]cobalt(II)
title_sort monoclinic polymorph of trans-tetra­aquabis­[(4-pyridylsulfanyl)­acetato-κn]cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961997/
https://www.ncbi.nlm.nih.gov/pubmed/21203067
http://dx.doi.org/10.1107/S1600536808023593
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AT moncoljan monoclinicpolymorphoftranstetraaquabis4pyridylsulfanylacetatokncobaltii
AT seglapeter monoclinicpolymorphoftranstetraaquabis4pyridylsulfanylacetatokncobaltii
AT komanmarian monoclinicpolymorphoftranstetraaquabis4pyridylsulfanylacetatokncobaltii

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