Cargando…
{(E)-2-[3-(Dimethylammonio)propyliminomethyl]phenolato}diiodidozinc(II)
The title complex, [ZnI(2)(C(12)H(18)N(2)O)], is a mononuclear zinc(II) compound derived from the zwitterionic form of the Schiff base (E)-2-[(3-dimethylaminopropylimino)methyl]phenol. The Zn(II) atom is four-coordinated by the imine N and phenolate O atoms of the Schiff base ligand, and by two...
Autores principales: | , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961998/ https://www.ncbi.nlm.nih.gov/pubmed/21203068 http://dx.doi.org/10.1107/S1600536808023659 |
_version_ | 1782189116358656000 |
---|---|
author | Zhu, Xue-Wen Yang, Xu-Zhao |
author_facet | Zhu, Xue-Wen Yang, Xu-Zhao |
author_sort | Zhu, Xue-Wen |
collection | PubMed |
description | The title complex, [ZnI(2)(C(12)H(18)N(2)O)], is a mononuclear zinc(II) compound derived from the zwitterionic form of the Schiff base (E)-2-[(3-dimethylaminopropylimino)methyl]phenol. The Zn(II) atom is four-coordinated by the imine N and phenolate O atoms of the Schiff base ligand, and by two iodide ions in a tetrahedral coordination geometry. In the crystal structure, molecules are linked through intermolecular N—H⋯O hydrogen bonds, forming chains running along the b axis. |
format | Text |
id | pubmed-2961998 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29619982010-12-30 {(E)-2-[3-(Dimethylammonio)propyliminomethyl]phenolato}diiodidozinc(II) Zhu, Xue-Wen Yang, Xu-Zhao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [ZnI(2)(C(12)H(18)N(2)O)], is a mononuclear zinc(II) compound derived from the zwitterionic form of the Schiff base (E)-2-[(3-dimethylaminopropylimino)methyl]phenol. The Zn(II) atom is four-coordinated by the imine N and phenolate O atoms of the Schiff base ligand, and by two iodide ions in a tetrahedral coordination geometry. In the crystal structure, molecules are linked through intermolecular N—H⋯O hydrogen bonds, forming chains running along the b axis. International Union of Crystallography 2008-07-31 /pmc/articles/PMC2961998/ /pubmed/21203068 http://dx.doi.org/10.1107/S1600536808023659 Text en © Zhu and Yang 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhu, Xue-Wen Yang, Xu-Zhao {(E)-2-[3-(Dimethylammonio)propyliminomethyl]phenolato}diiodidozinc(II) |
title | {(E)-2-[3-(Dimethylammonio)propyliminomethyl]phenolato}diiodidozinc(II) |
title_full | {(E)-2-[3-(Dimethylammonio)propyliminomethyl]phenolato}diiodidozinc(II) |
title_fullStr | {(E)-2-[3-(Dimethylammonio)propyliminomethyl]phenolato}diiodidozinc(II) |
title_full_unstemmed | {(E)-2-[3-(Dimethylammonio)propyliminomethyl]phenolato}diiodidozinc(II) |
title_short | {(E)-2-[3-(Dimethylammonio)propyliminomethyl]phenolato}diiodidozinc(II) |
title_sort | {(e)-2-[3-(dimethylammonio)propyliminomethyl]phenolato}diiodidozinc(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961998/ https://www.ncbi.nlm.nih.gov/pubmed/21203068 http://dx.doi.org/10.1107/S1600536808023659 |
work_keys_str_mv | AT zhuxuewen e23dimethylammoniopropyliminomethylphenolatodiiodidozincii AT yangxuzhao e23dimethylammoniopropyliminomethylphenolatodiiodidozincii |