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Dibromido{(E)-2-ethoxy-6-[3-(methylammonio)propyliminomethyl]phenolato}zinc(II)
The title complex, [ZnBr(2)(C(13)H(20)N(2)O(2))], is a mononuclear zinc(II) compound derived from the zwitterionic form of the Schiff base (E)-2-ethoxy-6-((3-(methylamino)propylimino)methyl)phenol. The Zn(II) atom is four-coordinated by the imine N and phenolate O atoms of the Schiff base ligand...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961999/ https://www.ncbi.nlm.nih.gov/pubmed/21203069 http://dx.doi.org/10.1107/S1600536808023672 |
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author | Zhu, Xue-Wen Yang, Xu-Zhao |
author_facet | Zhu, Xue-Wen Yang, Xu-Zhao |
author_sort | Zhu, Xue-Wen |
collection | PubMed |
description | The title complex, [ZnBr(2)(C(13)H(20)N(2)O(2))], is a mononuclear zinc(II) compound derived from the zwitterionic form of the Schiff base (E)-2-ethoxy-6-((3-(methylamino)propylimino)methyl)phenol. The Zn(II) atom is four-coordinated by the imine N and phenolate O atoms of the Schiff base ligand, and by two bromide ions, in a tetrahedral coordination geometry. Adjacent molecules are linked through intermolecular N—H⋯O hydrogen bonds, forming chains running along the b axis. |
format | Text |
id | pubmed-2961999 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29619992010-12-30 Dibromido{(E)-2-ethoxy-6-[3-(methylammonio)propyliminomethyl]phenolato}zinc(II) Zhu, Xue-Wen Yang, Xu-Zhao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [ZnBr(2)(C(13)H(20)N(2)O(2))], is a mononuclear zinc(II) compound derived from the zwitterionic form of the Schiff base (E)-2-ethoxy-6-((3-(methylamino)propylimino)methyl)phenol. The Zn(II) atom is four-coordinated by the imine N and phenolate O atoms of the Schiff base ligand, and by two bromide ions, in a tetrahedral coordination geometry. Adjacent molecules are linked through intermolecular N—H⋯O hydrogen bonds, forming chains running along the b axis. International Union of Crystallography 2008-07-31 /pmc/articles/PMC2961999/ /pubmed/21203069 http://dx.doi.org/10.1107/S1600536808023672 Text en © Zhu and Yang 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhu, Xue-Wen Yang, Xu-Zhao Dibromido{(E)-2-ethoxy-6-[3-(methylammonio)propyliminomethyl]phenolato}zinc(II) |
title | Dibromido{(E)-2-ethoxy-6-[3-(methylammonio)propyliminomethyl]phenolato}zinc(II) |
title_full | Dibromido{(E)-2-ethoxy-6-[3-(methylammonio)propyliminomethyl]phenolato}zinc(II) |
title_fullStr | Dibromido{(E)-2-ethoxy-6-[3-(methylammonio)propyliminomethyl]phenolato}zinc(II) |
title_full_unstemmed | Dibromido{(E)-2-ethoxy-6-[3-(methylammonio)propyliminomethyl]phenolato}zinc(II) |
title_short | Dibromido{(E)-2-ethoxy-6-[3-(methylammonio)propyliminomethyl]phenolato}zinc(II) |
title_sort | dibromido{(e)-2-ethoxy-6-[3-(methylammonio)propyliminomethyl]phenolato}zinc(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961999/ https://www.ncbi.nlm.nih.gov/pubmed/21203069 http://dx.doi.org/10.1107/S1600536808023672 |
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