Dibromido[N-propyl-N′-(2-pyridylmethyl­idene)ethane-1,2-diamine]zinc(II)

The title complex, [ZnBr(2)(C(11)H(17)N(3))], is a mononuclear zinc(II) compound derived from the Schiff base N-propyl-N′-(1-pyridin-2-ylmethyl­idene)ethane-1,2-diamine. The Zn(II) atom is five-coordinate, binding to the imine N, pyridine N, and amine N atoms of the Schiff base ligand and to two bro...

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Detalles Bibliográficos
Autores principales: Zhu, Xue-Wen, Yang, Xu-Zhao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962000/
https://www.ncbi.nlm.nih.gov/pubmed/21203070
http://dx.doi.org/10.1107/S1600536808023660
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author Zhu, Xue-Wen
Yang, Xu-Zhao
author_facet Zhu, Xue-Wen
Yang, Xu-Zhao
author_sort Zhu, Xue-Wen
collection PubMed
description The title complex, [ZnBr(2)(C(11)H(17)N(3))], is a mononuclear zinc(II) compound derived from the Schiff base N-propyl-N′-(1-pyridin-2-ylmethyl­idene)ethane-1,2-diamine. The Zn(II) atom is five-coordinate, binding to the imine N, pyridine N, and amine N atoms of the Schiff base ligand and to two bromide anions in a distorted trigonal-bipyramidal coordination geometry. Adjacent mol­ecules are linked through inter­molecular N—H⋯Br hydrogen bonds, forming dimers.
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spelling pubmed-29620002010-12-30 Dibromido[N-propyl-N′-(2-pyridylmethyl­idene)ethane-1,2-diamine]zinc(II) Zhu, Xue-Wen Yang, Xu-Zhao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [ZnBr(2)(C(11)H(17)N(3))], is a mononuclear zinc(II) compound derived from the Schiff base N-propyl-N′-(1-pyridin-2-ylmethyl­idene)ethane-1,2-diamine. The Zn(II) atom is five-coordinate, binding to the imine N, pyridine N, and amine N atoms of the Schiff base ligand and to two bromide anions in a distorted trigonal-bipyramidal coordination geometry. Adjacent mol­ecules are linked through inter­molecular N—H⋯Br hydrogen bonds, forming dimers. International Union of Crystallography 2008-07-31 /pmc/articles/PMC2962000/ /pubmed/21203070 http://dx.doi.org/10.1107/S1600536808023660 Text en © Zhu and Yang 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhu, Xue-Wen
Yang, Xu-Zhao
Dibromido[N-propyl-N′-(2-pyridylmethyl­idene)ethane-1,2-diamine]zinc(II)
title Dibromido[N-propyl-N′-(2-pyridylmethyl­idene)ethane-1,2-diamine]zinc(II)
title_full Dibromido[N-propyl-N′-(2-pyridylmethyl­idene)ethane-1,2-diamine]zinc(II)
title_fullStr Dibromido[N-propyl-N′-(2-pyridylmethyl­idene)ethane-1,2-diamine]zinc(II)
title_full_unstemmed Dibromido[N-propyl-N′-(2-pyridylmethyl­idene)ethane-1,2-diamine]zinc(II)
title_short Dibromido[N-propyl-N′-(2-pyridylmethyl­idene)ethane-1,2-diamine]zinc(II)
title_sort dibromido[n-propyl-n′-(2-pyridylmethyl­idene)ethane-1,2-diamine]zinc(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962000/
https://www.ncbi.nlm.nih.gov/pubmed/21203070
http://dx.doi.org/10.1107/S1600536808023660
work_keys_str_mv AT zhuxuewen dibromidonpropyln2pyridylmethylideneethane12diaminezincii
AT yangxuzhao dibromidonpropyln2pyridylmethylideneethane12diaminezincii

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