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Bis{(E)-2-ethoxy-6-[2-(ethylammonio)ethyliminomethyl]phenolato}nickel(II) bis(perchlorate)
In the title centrosymmetric mononuclear nickel(II) complex, [Ni(C(13)H(20)N(2)O(2))(2)](ClO(4))(2), the Ni(II) atom is four-coordinated by the imine N and phenolate O atoms of the zwitterionic forms of two Schiff base ligands in a square-planar coordination geometry. In the crystal structure, mole...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962001/ https://www.ncbi.nlm.nih.gov/pubmed/21203071 http://dx.doi.org/10.1107/S1600536808023684 |
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author | Zhu, Xue-Wen Yang, Xu-Zhao |
author_facet | Zhu, Xue-Wen Yang, Xu-Zhao |
author_sort | Zhu, Xue-Wen |
collection | PubMed |
description | In the title centrosymmetric mononuclear nickel(II) complex, [Ni(C(13)H(20)N(2)O(2))(2)](ClO(4))(2), the Ni(II) atom is four-coordinated by the imine N and phenolate O atoms of the zwitterionic forms of two Schiff base ligands in a square-planar coordination geometry. In the crystal structure, molecules are linked through intermolecular N—H⋯O hydrogen bonds, forming chains running along the a axis. |
format | Text |
id | pubmed-2962001 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29620012010-12-30 Bis{(E)-2-ethoxy-6-[2-(ethylammonio)ethyliminomethyl]phenolato}nickel(II) bis(perchlorate) Zhu, Xue-Wen Yang, Xu-Zhao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title centrosymmetric mononuclear nickel(II) complex, [Ni(C(13)H(20)N(2)O(2))(2)](ClO(4))(2), the Ni(II) atom is four-coordinated by the imine N and phenolate O atoms of the zwitterionic forms of two Schiff base ligands in a square-planar coordination geometry. In the crystal structure, molecules are linked through intermolecular N—H⋯O hydrogen bonds, forming chains running along the a axis. International Union of Crystallography 2008-07-31 /pmc/articles/PMC2962001/ /pubmed/21203071 http://dx.doi.org/10.1107/S1600536808023684 Text en © Zhu and Yang 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhu, Xue-Wen Yang, Xu-Zhao Bis{(E)-2-ethoxy-6-[2-(ethylammonio)ethyliminomethyl]phenolato}nickel(II) bis(perchlorate) |
title | Bis{(E)-2-ethoxy-6-[2-(ethylammonio)ethyliminomethyl]phenolato}nickel(II) bis(perchlorate) |
title_full | Bis{(E)-2-ethoxy-6-[2-(ethylammonio)ethyliminomethyl]phenolato}nickel(II) bis(perchlorate) |
title_fullStr | Bis{(E)-2-ethoxy-6-[2-(ethylammonio)ethyliminomethyl]phenolato}nickel(II) bis(perchlorate) |
title_full_unstemmed | Bis{(E)-2-ethoxy-6-[2-(ethylammonio)ethyliminomethyl]phenolato}nickel(II) bis(perchlorate) |
title_short | Bis{(E)-2-ethoxy-6-[2-(ethylammonio)ethyliminomethyl]phenolato}nickel(II) bis(perchlorate) |
title_sort | bis{(e)-2-ethoxy-6-[2-(ethylammonio)ethyliminomethyl]phenolato}nickel(ii) bis(perchlorate) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962001/ https://www.ncbi.nlm.nih.gov/pubmed/21203071 http://dx.doi.org/10.1107/S1600536808023684 |
work_keys_str_mv | AT zhuxuewen bise2ethoxy62ethylammonioethyliminomethylphenolatonickeliibisperchlorate AT yangxuzhao bise2ethoxy62ethylammonioethyliminomethylphenolatonickeliibisperchlorate |