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Bis{(E)-2-eth­oxy-6-[2-(ethyl­ammonio)ethyl­iminometh­yl]phenolato}nickel(II) bis(perchlorate)

In the title centrosymmetric mononuclear nickel(II) complex, [Ni(C(13)H(20)N(2)O(2))(2)](ClO(4))(2), the Ni(II) atom is four-coordinated by the imine N and phenolate O atoms of the zwitterionic forms of two Schiff base ligands in a square-planar coordination geometry. In the crystal structure, mol­e...

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Detalles Bibliográficos
Autores principales: Zhu, Xue-Wen, Yang, Xu-Zhao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962001/
https://www.ncbi.nlm.nih.gov/pubmed/21203071
http://dx.doi.org/10.1107/S1600536808023684
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author Zhu, Xue-Wen
Yang, Xu-Zhao
author_facet Zhu, Xue-Wen
Yang, Xu-Zhao
author_sort Zhu, Xue-Wen
collection PubMed
description In the title centrosymmetric mononuclear nickel(II) complex, [Ni(C(13)H(20)N(2)O(2))(2)](ClO(4))(2), the Ni(II) atom is four-coordinated by the imine N and phenolate O atoms of the zwitterionic forms of two Schiff base ligands in a square-planar coordination geometry. In the crystal structure, mol­ecules are linked through inter­molecular N—H⋯O hydrogen bonds, forming chains running along the a axis.
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spelling pubmed-29620012010-12-30 Bis{(E)-2-eth­oxy-6-[2-(ethyl­ammonio)ethyl­iminometh­yl]phenolato}nickel(II) bis(perchlorate) Zhu, Xue-Wen Yang, Xu-Zhao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title centrosymmetric mononuclear nickel(II) complex, [Ni(C(13)H(20)N(2)O(2))(2)](ClO(4))(2), the Ni(II) atom is four-coordinated by the imine N and phenolate O atoms of the zwitterionic forms of two Schiff base ligands in a square-planar coordination geometry. In the crystal structure, mol­ecules are linked through inter­molecular N—H⋯O hydrogen bonds, forming chains running along the a axis. International Union of Crystallography 2008-07-31 /pmc/articles/PMC2962001/ /pubmed/21203071 http://dx.doi.org/10.1107/S1600536808023684 Text en © Zhu and Yang 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhu, Xue-Wen
Yang, Xu-Zhao
Bis{(E)-2-eth­oxy-6-[2-(ethyl­ammonio)ethyl­iminometh­yl]phenolato}nickel(II) bis(perchlorate)
title Bis{(E)-2-eth­oxy-6-[2-(ethyl­ammonio)ethyl­iminometh­yl]phenolato}nickel(II) bis(perchlorate)
title_full Bis{(E)-2-eth­oxy-6-[2-(ethyl­ammonio)ethyl­iminometh­yl]phenolato}nickel(II) bis(perchlorate)
title_fullStr Bis{(E)-2-eth­oxy-6-[2-(ethyl­ammonio)ethyl­iminometh­yl]phenolato}nickel(II) bis(perchlorate)
title_full_unstemmed Bis{(E)-2-eth­oxy-6-[2-(ethyl­ammonio)ethyl­iminometh­yl]phenolato}nickel(II) bis(perchlorate)
title_short Bis{(E)-2-eth­oxy-6-[2-(ethyl­ammonio)ethyl­iminometh­yl]phenolato}nickel(II) bis(perchlorate)
title_sort bis{(e)-2-eth­oxy-6-[2-(ethyl­ammonio)ethyl­iminometh­yl]phenolato}nickel(ii) bis(perchlorate)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962001/
https://www.ncbi.nlm.nih.gov/pubmed/21203071
http://dx.doi.org/10.1107/S1600536808023684
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