Cargando…

catena-Poly[[[diaqua­terbium(III)]-tri-μ(2)-isonicotinato-κ(6) O:O′] tris(perchlorate) monohydrate]

In the title complex, {[Tb(C(6)H(5)NO(2))(3)(H(2)O)(2)](ClO(4))(3)·H(2)O}(n), the Tb(III) ion is coordinated by six O atoms from six isonicotinate (inic) ligands and two water mol­ecules, displaying a bicapped trigonal-prismatic geometry. The inic ligands, which are protonated at the pyridine N atom...

Descripción completa

Detalles Bibliográficos
Autores principales: Huang, Xiao-Hui, Pan, Wei-Bo, Xu, Xiao-Hong, Zeng, Rong-Hua
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962002/
https://www.ncbi.nlm.nih.gov/pubmed/21203072
http://dx.doi.org/10.1107/S1600536808023623
Descripción
Sumario:In the title complex, {[Tb(C(6)H(5)NO(2))(3)(H(2)O)(2)](ClO(4))(3)·H(2)O}(n), the Tb(III) ion is coordinated by six O atoms from six isonicotinate (inic) ligands and two water mol­ecules, displaying a bicapped trigonal-prismatic geometry. The inic ligands, which are protonated at the pyridine N atom, link the metal centres, forming a polymeric chain running parallel to the a axis. The chains are further assembled via intra- and inter­molecular O—H⋯O and N—H⋯O hydrogen-bonding inter­actions into a three-dimensional supra­molecular network involving the inic ligands, the water mol­ecules and the perchlorate anions. One of the perchlorate ions is disordered over two sites with occupancies of 0.561 (17) and 0.439 (17).