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catena-Poly[[[diaquaterbium(III)]-tri-μ(2)-isonicotinato-κ(6) O:O′] tris(perchlorate) monohydrate]
In the title complex, {[Tb(C(6)H(5)NO(2))(3)(H(2)O)(2)](ClO(4))(3)·H(2)O}(n), the Tb(III) ion is coordinated by six O atoms from six isonicotinate (inic) ligands and two water molecules, displaying a bicapped trigonal-prismatic geometry. The inic ligands, which are protonated at the pyridine N atom...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962002/ https://www.ncbi.nlm.nih.gov/pubmed/21203072 http://dx.doi.org/10.1107/S1600536808023623 |
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author | Huang, Xiao-Hui Pan, Wei-Bo Xu, Xiao-Hong Zeng, Rong-Hua |
author_facet | Huang, Xiao-Hui Pan, Wei-Bo Xu, Xiao-Hong Zeng, Rong-Hua |
author_sort | Huang, Xiao-Hui |
collection | PubMed |
description | In the title complex, {[Tb(C(6)H(5)NO(2))(3)(H(2)O)(2)](ClO(4))(3)·H(2)O}(n), the Tb(III) ion is coordinated by six O atoms from six isonicotinate (inic) ligands and two water molecules, displaying a bicapped trigonal-prismatic geometry. The inic ligands, which are protonated at the pyridine N atom, link the metal centres, forming a polymeric chain running parallel to the a axis. The chains are further assembled via intra- and intermolecular O—H⋯O and N—H⋯O hydrogen-bonding interactions into a three-dimensional supramolecular network involving the inic ligands, the water molecules and the perchlorate anions. One of the perchlorate ions is disordered over two sites with occupancies of 0.561 (17) and 0.439 (17). |
format | Text |
id | pubmed-2962002 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29620022010-12-30 catena-Poly[[[diaquaterbium(III)]-tri-μ(2)-isonicotinato-κ(6) O:O′] tris(perchlorate) monohydrate] Huang, Xiao-Hui Pan, Wei-Bo Xu, Xiao-Hong Zeng, Rong-Hua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, {[Tb(C(6)H(5)NO(2))(3)(H(2)O)(2)](ClO(4))(3)·H(2)O}(n), the Tb(III) ion is coordinated by six O atoms from six isonicotinate (inic) ligands and two water molecules, displaying a bicapped trigonal-prismatic geometry. The inic ligands, which are protonated at the pyridine N atom, link the metal centres, forming a polymeric chain running parallel to the a axis. The chains are further assembled via intra- and intermolecular O—H⋯O and N—H⋯O hydrogen-bonding interactions into a three-dimensional supramolecular network involving the inic ligands, the water molecules and the perchlorate anions. One of the perchlorate ions is disordered over two sites with occupancies of 0.561 (17) and 0.439 (17). International Union of Crystallography 2008-07-31 /pmc/articles/PMC2962002/ /pubmed/21203072 http://dx.doi.org/10.1107/S1600536808023623 Text en © Xiao-Hui et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Huang, Xiao-Hui Pan, Wei-Bo Xu, Xiao-Hong Zeng, Rong-Hua catena-Poly[[[diaquaterbium(III)]-tri-μ(2)-isonicotinato-κ(6) O:O′] tris(perchlorate) monohydrate] |
title |
catena-Poly[[[diaquaterbium(III)]-tri-μ(2)-isonicotinato-κ(6)
O:O′] tris(perchlorate) monohydrate] |
title_full |
catena-Poly[[[diaquaterbium(III)]-tri-μ(2)-isonicotinato-κ(6)
O:O′] tris(perchlorate) monohydrate] |
title_fullStr |
catena-Poly[[[diaquaterbium(III)]-tri-μ(2)-isonicotinato-κ(6)
O:O′] tris(perchlorate) monohydrate] |
title_full_unstemmed |
catena-Poly[[[diaquaterbium(III)]-tri-μ(2)-isonicotinato-κ(6)
O:O′] tris(perchlorate) monohydrate] |
title_short |
catena-Poly[[[diaquaterbium(III)]-tri-μ(2)-isonicotinato-κ(6)
O:O′] tris(perchlorate) monohydrate] |
title_sort | catena-poly[[[diaquaterbium(iii)]-tri-μ(2)-isonicotinato-κ(6)
o:o′] tris(perchlorate) monohydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962002/ https://www.ncbi.nlm.nih.gov/pubmed/21203072 http://dx.doi.org/10.1107/S1600536808023623 |
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