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catena-Poly[[[diaqua­terbium(III)]-tri-μ(2)-isonicotinato-κ(6) O:O′] tris(perchlorate) monohydrate]

In the title complex, {[Tb(C(6)H(5)NO(2))(3)(H(2)O)(2)](ClO(4))(3)·H(2)O}(n), the Tb(III) ion is coordinated by six O atoms from six isonicotinate (inic) ligands and two water mol­ecules, displaying a bicapped trigonal-prismatic geometry. The inic ligands, which are protonated at the pyridine N atom...

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Detalles Bibliográficos
Autores principales: Huang, Xiao-Hui, Pan, Wei-Bo, Xu, Xiao-Hong, Zeng, Rong-Hua
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962002/
https://www.ncbi.nlm.nih.gov/pubmed/21203072
http://dx.doi.org/10.1107/S1600536808023623
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author Huang, Xiao-Hui
Pan, Wei-Bo
Xu, Xiao-Hong
Zeng, Rong-Hua
author_facet Huang, Xiao-Hui
Pan, Wei-Bo
Xu, Xiao-Hong
Zeng, Rong-Hua
author_sort Huang, Xiao-Hui
collection PubMed
description In the title complex, {[Tb(C(6)H(5)NO(2))(3)(H(2)O)(2)](ClO(4))(3)·H(2)O}(n), the Tb(III) ion is coordinated by six O atoms from six isonicotinate (inic) ligands and two water mol­ecules, displaying a bicapped trigonal-prismatic geometry. The inic ligands, which are protonated at the pyridine N atom, link the metal centres, forming a polymeric chain running parallel to the a axis. The chains are further assembled via intra- and inter­molecular O—H⋯O and N—H⋯O hydrogen-bonding inter­actions into a three-dimensional supra­molecular network involving the inic ligands, the water mol­ecules and the perchlorate anions. One of the perchlorate ions is disordered over two sites with occupancies of 0.561 (17) and 0.439 (17).
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spelling pubmed-29620022010-12-30 catena-Poly[[[diaqua­terbium(III)]-tri-μ(2)-isonicotinato-κ(6) O:O′] tris(perchlorate) monohydrate] Huang, Xiao-Hui Pan, Wei-Bo Xu, Xiao-Hong Zeng, Rong-Hua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, {[Tb(C(6)H(5)NO(2))(3)(H(2)O)(2)](ClO(4))(3)·H(2)O}(n), the Tb(III) ion is coordinated by six O atoms from six isonicotinate (inic) ligands and two water mol­ecules, displaying a bicapped trigonal-prismatic geometry. The inic ligands, which are protonated at the pyridine N atom, link the metal centres, forming a polymeric chain running parallel to the a axis. The chains are further assembled via intra- and inter­molecular O—H⋯O and N—H⋯O hydrogen-bonding inter­actions into a three-dimensional supra­molecular network involving the inic ligands, the water mol­ecules and the perchlorate anions. One of the perchlorate ions is disordered over two sites with occupancies of 0.561 (17) and 0.439 (17). International Union of Crystallography 2008-07-31 /pmc/articles/PMC2962002/ /pubmed/21203072 http://dx.doi.org/10.1107/S1600536808023623 Text en © Xiao-Hui et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Huang, Xiao-Hui
Pan, Wei-Bo
Xu, Xiao-Hong
Zeng, Rong-Hua
catena-Poly[[[diaqua­terbium(III)]-tri-μ(2)-isonicotinato-κ(6) O:O′] tris(perchlorate) monohydrate]
title catena-Poly[[[diaqua­terbium(III)]-tri-μ(2)-isonicotinato-κ(6) O:O′] tris(perchlorate) monohydrate]
title_full catena-Poly[[[diaqua­terbium(III)]-tri-μ(2)-isonicotinato-κ(6) O:O′] tris(perchlorate) monohydrate]
title_fullStr catena-Poly[[[diaqua­terbium(III)]-tri-μ(2)-isonicotinato-κ(6) O:O′] tris(perchlorate) monohydrate]
title_full_unstemmed catena-Poly[[[diaqua­terbium(III)]-tri-μ(2)-isonicotinato-κ(6) O:O′] tris(perchlorate) monohydrate]
title_short catena-Poly[[[diaqua­terbium(III)]-tri-μ(2)-isonicotinato-κ(6) O:O′] tris(perchlorate) monohydrate]
title_sort catena-poly[[[diaqua­terbium(iii)]-tri-μ(2)-isonicotinato-κ(6) o:o′] tris(perchlorate) monohydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962002/
https://www.ncbi.nlm.nih.gov/pubmed/21203072
http://dx.doi.org/10.1107/S1600536808023623
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