catena-Poly[bis­[octa­kis(dimethyl sulf­oxide)praseodymium(III)] hexa-μ(3)-sulfido-dodeca-μ(2)-sulfido-hexa­sul­fido­hexa­silverhexa­molybdenum]

The title compound, {[Pr(C(2)H(6)OS)(8)](2)[Mo(6)Ag(6)S(24)]}(n), contains polymeric Mo(6)S(24)Ag(6) (2−) anions and [Pr(Me(2)SO)(8)](3+) cations, forming a one-dimensional polymeric Mo/S/Ag cluster. The anion assumes the conformation of a zigzag chain. The trivalent cations are arrayed amongst the...

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Detalles Bibliográficos
Autores principales: Jiang, Zhengjing, Tang, Guodong, Li, Rongqing, Zhang, Yu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962003/
https://www.ncbi.nlm.nih.gov/pubmed/21203073
http://dx.doi.org/10.1107/S1600536808023696
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author Jiang, Zhengjing
Tang, Guodong
Li, Rongqing
Zhang, Yu
author_facet Jiang, Zhengjing
Tang, Guodong
Li, Rongqing
Zhang, Yu
author_sort Jiang, Zhengjing
collection PubMed
description The title compound, {[Pr(C(2)H(6)OS)(8)](2)[Mo(6)Ag(6)S(24)]}(n), contains polymeric Mo(6)S(24)Ag(6) (2−) anions and [Pr(Me(2)SO)(8)](3+) cations, forming a one-dimensional polymeric Mo/S/Ag cluster. The anion assumes the conformation of a zigzag chain. The trivalent cations are arrayed amongst the anionic chains and are well separated from each other. Each Mo and Ag atom is coordinated by four S atoms in a distorted tetra­hedral geometry. The Pr(3+) atom is coordinated by eight dimethyl sulfoxide ligands, forming a polyhedron-shaped distorted square anti­prism.
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spelling pubmed-29620032010-12-30 catena-Poly[bis­[octa­kis(dimethyl sulf­oxide)praseodymium(III)] hexa-μ(3)-sulfido-dodeca-μ(2)-sulfido-hexa­sul­fido­hexa­silverhexa­molybdenum] Jiang, Zhengjing Tang, Guodong Li, Rongqing Zhang, Yu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, {[Pr(C(2)H(6)OS)(8)](2)[Mo(6)Ag(6)S(24)]}(n), contains polymeric Mo(6)S(24)Ag(6) (2−) anions and [Pr(Me(2)SO)(8)](3+) cations, forming a one-dimensional polymeric Mo/S/Ag cluster. The anion assumes the conformation of a zigzag chain. The trivalent cations are arrayed amongst the anionic chains and are well separated from each other. Each Mo and Ag atom is coordinated by four S atoms in a distorted tetra­hedral geometry. The Pr(3+) atom is coordinated by eight dimethyl sulfoxide ligands, forming a polyhedron-shaped distorted square anti­prism. International Union of Crystallography 2008-07-31 /pmc/articles/PMC2962003/ /pubmed/21203073 http://dx.doi.org/10.1107/S1600536808023696 Text en © Jiang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Jiang, Zhengjing
Tang, Guodong
Li, Rongqing
Zhang, Yu
catena-Poly[bis­[octa­kis(dimethyl sulf­oxide)praseodymium(III)] hexa-μ(3)-sulfido-dodeca-μ(2)-sulfido-hexa­sul­fido­hexa­silverhexa­molybdenum]
title catena-Poly[bis­[octa­kis(dimethyl sulf­oxide)praseodymium(III)] hexa-μ(3)-sulfido-dodeca-μ(2)-sulfido-hexa­sul­fido­hexa­silverhexa­molybdenum]
title_full catena-Poly[bis­[octa­kis(dimethyl sulf­oxide)praseodymium(III)] hexa-μ(3)-sulfido-dodeca-μ(2)-sulfido-hexa­sul­fido­hexa­silverhexa­molybdenum]
title_fullStr catena-Poly[bis­[octa­kis(dimethyl sulf­oxide)praseodymium(III)] hexa-μ(3)-sulfido-dodeca-μ(2)-sulfido-hexa­sul­fido­hexa­silverhexa­molybdenum]
title_full_unstemmed catena-Poly[bis­[octa­kis(dimethyl sulf­oxide)praseodymium(III)] hexa-μ(3)-sulfido-dodeca-μ(2)-sulfido-hexa­sul­fido­hexa­silverhexa­molybdenum]
title_short catena-Poly[bis­[octa­kis(dimethyl sulf­oxide)praseodymium(III)] hexa-μ(3)-sulfido-dodeca-μ(2)-sulfido-hexa­sul­fido­hexa­silverhexa­molybdenum]
title_sort catena-poly[bis­[octa­kis(dimethyl sulf­oxide)praseodymium(iii)] hexa-μ(3)-sulfido-dodeca-μ(2)-sulfido-hexa­sul­fido­hexa­silverhexa­molybdenum]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962003/
https://www.ncbi.nlm.nih.gov/pubmed/21203073
http://dx.doi.org/10.1107/S1600536808023696
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