Octa-n-butyl-1κ (2) C,2κ (2) C,3κ (2) C,4κ (2) C-tetra­kis(μ-2-hydroxy­benzoato)-1:2κ (2) O:O;2:3κ(2) O:O′;3:4κ (2) O:O;1:4κ (2) O:O′-di-μ (3)-oxido-1:2:3κ (3) O:O:O;1:3:4κ (3) O:O:O-tetra­tin(IV)

In the centrosymmetric tetra­nuclear title compound, [Sn(4)(C(4)H(9))(8)(C(7)H(5)O(3))(4)O(2)], one of the two independent Sn atoms is five-coordinate in a cis-C(2)SnO(3) trigonal-bipyramidal geometry [C—Sn—C = 142.7 (1)°]; the geometry is distorted owing to a long Sn⋯O(double bond) inter­action [Sn...

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Detalles Bibliográficos
Autores principales: Reisi, Reza, Siti Munirah, Shahirin, Misran, Misni, Lo, Kong Mun, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962005/
https://www.ncbi.nlm.nih.gov/pubmed/21203075
http://dx.doi.org/10.1107/S1600536808023787
Descripción
Sumario:In the centrosymmetric tetra­nuclear title compound, [Sn(4)(C(4)H(9))(8)(C(7)H(5)O(3))(4)O(2)], one of the two independent Sn atoms is five-coordinate in a cis-C(2)SnO(3) trigonal-bipyramidal geometry [C—Sn—C = 142.7 (1)°]; the geometry is distorted owing to a long Sn⋯O(double bond) inter­action [Sn⋯O = 2.862 (1) Å]. The other Sn atom has a bent R (2)Sn skeleton [C—Sn—C = 144.0 (1)°], but the geometry is best regarded as being a trans-C(2)SnO(4) octa­hedron as the Sn–O(single bond) inter­action is shorter [Sn—O = 2.674 (1) Å].

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