N,N′-Bis(4-bromo­benzyl­idene)ethane-1,2-diamine

The mol­ecule of the title Schiff base compound, C(16)H(14)Br(2)N(2), lies across a crystallographic inversion centre and adopts an E configuration with respect to the azomethine C=N bond. The imino group is coplanar with the aromatic ring. Within the mol­ecule, the planar units are parallel, but ex...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Mirkhani, Valiollah, Kia, Reza, Vartooni, Akbar Rostami
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962009/
https://www.ncbi.nlm.nih.gov/pubmed/21203096
http://dx.doi.org/10.1107/S1600536808019594
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author Fun, Hoong-Kun
Mirkhani, Valiollah
Kia, Reza
Vartooni, Akbar Rostami
author_facet Fun, Hoong-Kun
Mirkhani, Valiollah
Kia, Reza
Vartooni, Akbar Rostami
author_sort Fun, Hoong-Kun
collection PubMed
description The mol­ecule of the title Schiff base compound, C(16)H(14)Br(2)N(2), lies across a crystallographic inversion centre and adopts an E configuration with respect to the azomethine C=N bond. The imino group is coplanar with the aromatic ring. Within the mol­ecule, the planar units are parallel, but extend in opposite directions from the dimethyl­ene bridge. The crystal structure is stabilized by inter­molecular C—H⋯π inter­actions and Br⋯Br [3.6307 (4) Å] short contacts.
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spelling pubmed-29620092010-12-30 N,N′-Bis(4-bromo­benzyl­idene)ethane-1,2-diamine Fun, Hoong-Kun Mirkhani, Valiollah Kia, Reza Vartooni, Akbar Rostami Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecule of the title Schiff base compound, C(16)H(14)Br(2)N(2), lies across a crystallographic inversion centre and adopts an E configuration with respect to the azomethine C=N bond. The imino group is coplanar with the aromatic ring. Within the mol­ecule, the planar units are parallel, but extend in opposite directions from the dimethyl­ene bridge. The crystal structure is stabilized by inter­molecular C—H⋯π inter­actions and Br⋯Br [3.6307 (4) Å] short contacts. International Union of Crystallography 2008-07-05 /pmc/articles/PMC2962009/ /pubmed/21203096 http://dx.doi.org/10.1107/S1600536808019594 Text en © Fun et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Mirkhani, Valiollah
Kia, Reza
Vartooni, Akbar Rostami
N,N′-Bis(4-bromo­benzyl­idene)ethane-1,2-diamine
title N,N′-Bis(4-bromo­benzyl­idene)ethane-1,2-diamine
title_full N,N′-Bis(4-bromo­benzyl­idene)ethane-1,2-diamine
title_fullStr N,N′-Bis(4-bromo­benzyl­idene)ethane-1,2-diamine
title_full_unstemmed N,N′-Bis(4-bromo­benzyl­idene)ethane-1,2-diamine
title_short N,N′-Bis(4-bromo­benzyl­idene)ethane-1,2-diamine
title_sort n,n′-bis(4-bromo­benzyl­idene)ethane-1,2-diamine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962009/
https://www.ncbi.nlm.nih.gov/pubmed/21203096
http://dx.doi.org/10.1107/S1600536808019594
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AT vartooniakbarrostami nnbis4bromobenzylideneethane12diamine

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