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Diethyl {(4-methoxyphenyl)[5-(4-nitrophenyl)-1,3,4-thiadiazol-2-ylamino]methyl}phosphonate
The title compound, C(20)H(23)N(4)O(6)PS, was synthesized by the reaction of N-(4-methoxybenzylidene)-5-(4-nitrophenyl)-1,3,4-thiadiazol-2-amine and diethyl phosphite. The thiadiazole and nitro-substituted phenyl rings in the molecule are approximately coplanar, the dihedral angle being 5.3 (...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962010/ https://www.ncbi.nlm.nih.gov/pubmed/21203097 http://dx.doi.org/10.1107/S1600536808017364 |
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author | Yin, Li-He Wan, Rong Han, Feng Wang, Bin Wang, Jin-Tang |
author_facet | Yin, Li-He Wan, Rong Han, Feng Wang, Bin Wang, Jin-Tang |
author_sort | Yin, Li-He |
collection | PubMed |
description | The title compound, C(20)H(23)N(4)O(6)PS, was synthesized by the reaction of N-(4-methoxybenzylidene)-5-(4-nitrophenyl)-1,3,4-thiadiazol-2-amine and diethyl phosphite. The thiadiazole and nitro-substituted phenyl rings in the molecule are approximately coplanar, the dihedral angle being 5.3 (2)°. The dihedral angle formed by the mean plane through all non-H atoms of both the thiadiazole and the nitro-substituted phenyl ring with the plane of the methoxy-substituted phenyl ring is 48.9 (2)°. In the crystal structure, molecules form centrosymmetric dimers as a result of N—H⋯O bonds involving amine H and phosphine oxide O atoms. |
format | Text |
id | pubmed-2962010 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29620102010-12-30 Diethyl {(4-methoxyphenyl)[5-(4-nitrophenyl)-1,3,4-thiadiazol-2-ylamino]methyl}phosphonate Yin, Li-He Wan, Rong Han, Feng Wang, Bin Wang, Jin-Tang Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(20)H(23)N(4)O(6)PS, was synthesized by the reaction of N-(4-methoxybenzylidene)-5-(4-nitrophenyl)-1,3,4-thiadiazol-2-amine and diethyl phosphite. The thiadiazole and nitro-substituted phenyl rings in the molecule are approximately coplanar, the dihedral angle being 5.3 (2)°. The dihedral angle formed by the mean plane through all non-H atoms of both the thiadiazole and the nitro-substituted phenyl ring with the plane of the methoxy-substituted phenyl ring is 48.9 (2)°. In the crystal structure, molecules form centrosymmetric dimers as a result of N—H⋯O bonds involving amine H and phosphine oxide O atoms. International Union of Crystallography 2008-07-05 /pmc/articles/PMC2962010/ /pubmed/21203097 http://dx.doi.org/10.1107/S1600536808017364 Text en © Yin et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Yin, Li-He Wan, Rong Han, Feng Wang, Bin Wang, Jin-Tang Diethyl {(4-methoxyphenyl)[5-(4-nitrophenyl)-1,3,4-thiadiazol-2-ylamino]methyl}phosphonate |
title | Diethyl {(4-methoxyphenyl)[5-(4-nitrophenyl)-1,3,4-thiadiazol-2-ylamino]methyl}phosphonate |
title_full | Diethyl {(4-methoxyphenyl)[5-(4-nitrophenyl)-1,3,4-thiadiazol-2-ylamino]methyl}phosphonate |
title_fullStr | Diethyl {(4-methoxyphenyl)[5-(4-nitrophenyl)-1,3,4-thiadiazol-2-ylamino]methyl}phosphonate |
title_full_unstemmed | Diethyl {(4-methoxyphenyl)[5-(4-nitrophenyl)-1,3,4-thiadiazol-2-ylamino]methyl}phosphonate |
title_short | Diethyl {(4-methoxyphenyl)[5-(4-nitrophenyl)-1,3,4-thiadiazol-2-ylamino]methyl}phosphonate |
title_sort | diethyl {(4-methoxyphenyl)[5-(4-nitrophenyl)-1,3,4-thiadiazol-2-ylamino]methyl}phosphonate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962010/ https://www.ncbi.nlm.nih.gov/pubmed/21203097 http://dx.doi.org/10.1107/S1600536808017364 |
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