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Diethyl {(4-methoxy­phen­yl)[5-(4-nitro­phen­yl)-1,3,4-thia­diazol-2-ylamino]meth­yl}phospho­nate

The title compound, C(20)H(23)N(4)O(6)PS, was synthesized by the reaction of N-(4-methoxy­benzyl­idene)-5-(4-nitro­phen­yl)-1,3,4-thia­diazol-2-amine and diethyl phosphite. The thia­diazole and nitro-substituted phenyl rings in the mol­ecule are approximately coplanar, the dihedral angle being 5.3 (...

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Detalles Bibliográficos
Autores principales: Yin, Li-He, Wan, Rong, Han, Feng, Wang, Bin, Wang, Jin-Tang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962010/
https://www.ncbi.nlm.nih.gov/pubmed/21203097
http://dx.doi.org/10.1107/S1600536808017364
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author Yin, Li-He
Wan, Rong
Han, Feng
Wang, Bin
Wang, Jin-Tang
author_facet Yin, Li-He
Wan, Rong
Han, Feng
Wang, Bin
Wang, Jin-Tang
author_sort Yin, Li-He
collection PubMed
description The title compound, C(20)H(23)N(4)O(6)PS, was synthesized by the reaction of N-(4-methoxy­benzyl­idene)-5-(4-nitro­phen­yl)-1,3,4-thia­diazol-2-amine and diethyl phosphite. The thia­diazole and nitro-substituted phenyl rings in the mol­ecule are approximately coplanar, the dihedral angle being 5.3 (2)°. The dihedral angle formed by the mean plane through all non-H atoms of both the thia­diazole and the nitro-substituted phenyl ring with the plane of the meth­oxy-substituted phenyl ring is 48.9 (2)°. In the crystal structure, mol­ecules form centrosymmetric dimers as a result of N—H⋯O bonds involving amine H and phosphine oxide O atoms.
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spelling pubmed-29620102010-12-30 Diethyl {(4-methoxy­phen­yl)[5-(4-nitro­phen­yl)-1,3,4-thia­diazol-2-ylamino]meth­yl}phospho­nate Yin, Li-He Wan, Rong Han, Feng Wang, Bin Wang, Jin-Tang Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(20)H(23)N(4)O(6)PS, was synthesized by the reaction of N-(4-methoxy­benzyl­idene)-5-(4-nitro­phen­yl)-1,3,4-thia­diazol-2-amine and diethyl phosphite. The thia­diazole and nitro-substituted phenyl rings in the mol­ecule are approximately coplanar, the dihedral angle being 5.3 (2)°. The dihedral angle formed by the mean plane through all non-H atoms of both the thia­diazole and the nitro-substituted phenyl ring with the plane of the meth­oxy-substituted phenyl ring is 48.9 (2)°. In the crystal structure, mol­ecules form centrosymmetric dimers as a result of N—H⋯O bonds involving amine H and phosphine oxide O atoms. International Union of Crystallography 2008-07-05 /pmc/articles/PMC2962010/ /pubmed/21203097 http://dx.doi.org/10.1107/S1600536808017364 Text en © Yin et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Yin, Li-He
Wan, Rong
Han, Feng
Wang, Bin
Wang, Jin-Tang
Diethyl {(4-methoxy­phen­yl)[5-(4-nitro­phen­yl)-1,3,4-thia­diazol-2-ylamino]meth­yl}phospho­nate
title Diethyl {(4-methoxy­phen­yl)[5-(4-nitro­phen­yl)-1,3,4-thia­diazol-2-ylamino]meth­yl}phospho­nate
title_full Diethyl {(4-methoxy­phen­yl)[5-(4-nitro­phen­yl)-1,3,4-thia­diazol-2-ylamino]meth­yl}phospho­nate
title_fullStr Diethyl {(4-methoxy­phen­yl)[5-(4-nitro­phen­yl)-1,3,4-thia­diazol-2-ylamino]meth­yl}phospho­nate
title_full_unstemmed Diethyl {(4-methoxy­phen­yl)[5-(4-nitro­phen­yl)-1,3,4-thia­diazol-2-ylamino]meth­yl}phospho­nate
title_short Diethyl {(4-methoxy­phen­yl)[5-(4-nitro­phen­yl)-1,3,4-thia­diazol-2-ylamino]meth­yl}phospho­nate
title_sort diethyl {(4-methoxy­phen­yl)[5-(4-nitro­phen­yl)-1,3,4-thia­diazol-2-ylamino]meth­yl}phospho­nate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962010/
https://www.ncbi.nlm.nih.gov/pubmed/21203097
http://dx.doi.org/10.1107/S1600536808017364
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