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N-(4-Bromophenylsulfonyl)-2,2,2-trimethylacetamide
The conformations of the N—H and C=O bonds in the SO(2)—NH—CO—C group of the title compound (N4BPSTMAA), C(11)H(14)BrNO(3)S, are trans to each other, similar to what is observed in N-(4-chlorophenylsulfonyl)-2,2,2-trimethylacetamide (N4CPSTMAA) and 2,2,2-trimethyl-N-(4-methylphenylsulfonyl)...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962022/ https://www.ncbi.nlm.nih.gov/pubmed/21203109 http://dx.doi.org/10.1107/S1600536808019375 |
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author | Gowda, B. Thimme Foro, Sabine Nirmala, P. G. Sowmya, B. P. Fuess, Hartmut |
author_facet | Gowda, B. Thimme Foro, Sabine Nirmala, P. G. Sowmya, B. P. Fuess, Hartmut |
author_sort | Gowda, B. Thimme |
collection | PubMed |
description | The conformations of the N—H and C=O bonds in the SO(2)—NH—CO—C group of the title compound (N4BPSTMAA), C(11)H(14)BrNO(3)S, are trans to each other, similar to what is observed in N-(4-chlorophenylsulfonyl)-2,2,2-trimethylacetamide (N4CPSTMAA) and 2,2,2-trimethyl-N-(4-methylphenylsulfonyl)acetamide (N4MPSTMAA). The bond parameters in N4BPSTMAA are similar to those in N4CPSTMAA, N4MPSTMAA, N-aryl-2,2,2-trimethylacetamides and 4-bromobenzenesulfonamide. The benzene ring and the SO(2)—NH—CO—C group in N4BPSTMAA form a dihedral angle of 82.8 (1)°, comparable with the values of 82.2 (1)° in N4CPSTMAA and 71.2 (1)° in N4MPSTMAA. N—H⋯O hydrogen bonds form a centrosymmetric ring characterized by an R (2) (2)(8) motif. |
format | Text |
id | pubmed-2962022 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29620222010-12-30 N-(4-Bromophenylsulfonyl)-2,2,2-trimethylacetamide Gowda, B. Thimme Foro, Sabine Nirmala, P. G. Sowmya, B. P. Fuess, Hartmut Acta Crystallogr Sect E Struct Rep Online Organic Papers The conformations of the N—H and C=O bonds in the SO(2)—NH—CO—C group of the title compound (N4BPSTMAA), C(11)H(14)BrNO(3)S, are trans to each other, similar to what is observed in N-(4-chlorophenylsulfonyl)-2,2,2-trimethylacetamide (N4CPSTMAA) and 2,2,2-trimethyl-N-(4-methylphenylsulfonyl)acetamide (N4MPSTMAA). The bond parameters in N4BPSTMAA are similar to those in N4CPSTMAA, N4MPSTMAA, N-aryl-2,2,2-trimethylacetamides and 4-bromobenzenesulfonamide. The benzene ring and the SO(2)—NH—CO—C group in N4BPSTMAA form a dihedral angle of 82.8 (1)°, comparable with the values of 82.2 (1)° in N4CPSTMAA and 71.2 (1)° in N4MPSTMAA. N—H⋯O hydrogen bonds form a centrosymmetric ring characterized by an R (2) (2)(8) motif. International Union of Crystallography 2008-07-05 /pmc/articles/PMC2962022/ /pubmed/21203109 http://dx.doi.org/10.1107/S1600536808019375 Text en © Gowda et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Gowda, B. Thimme Foro, Sabine Nirmala, P. G. Sowmya, B. P. Fuess, Hartmut N-(4-Bromophenylsulfonyl)-2,2,2-trimethylacetamide |
title |
N-(4-Bromophenylsulfonyl)-2,2,2-trimethylacetamide |
title_full |
N-(4-Bromophenylsulfonyl)-2,2,2-trimethylacetamide |
title_fullStr |
N-(4-Bromophenylsulfonyl)-2,2,2-trimethylacetamide |
title_full_unstemmed |
N-(4-Bromophenylsulfonyl)-2,2,2-trimethylacetamide |
title_short |
N-(4-Bromophenylsulfonyl)-2,2,2-trimethylacetamide |
title_sort | n-(4-bromophenylsulfonyl)-2,2,2-trimethylacetamide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962022/ https://www.ncbi.nlm.nih.gov/pubmed/21203109 http://dx.doi.org/10.1107/S1600536808019375 |
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