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N-(4-Bromo­phenyl­sulfon­yl)-2,2,2-tri­methyl­acetamide

The conformations of the N—H and C=O bonds in the SO(2)—NH—CO—C group of the title compound (N4BPSTMAA), C(11)H(14)BrNO(3)S, are trans to each other, similar to what is observed in N-(4-chloro­phenyl­sulfon­yl)-2,2,2-trimethyl­acet­amide (N4CPSTMAA) and 2,2,2-trimethyl-N-(4-methyl­phenyl­­sulfon­yl)...

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Autores principales: Gowda, B. Thimme, Foro, Sabine, Nirmala, P. G., Sowmya, B. P., Fuess, Hartmut
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962022/
https://www.ncbi.nlm.nih.gov/pubmed/21203109
http://dx.doi.org/10.1107/S1600536808019375
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author Gowda, B. Thimme
Foro, Sabine
Nirmala, P. G.
Sowmya, B. P.
Fuess, Hartmut
author_facet Gowda, B. Thimme
Foro, Sabine
Nirmala, P. G.
Sowmya, B. P.
Fuess, Hartmut
author_sort Gowda, B. Thimme
collection PubMed
description The conformations of the N—H and C=O bonds in the SO(2)—NH—CO—C group of the title compound (N4BPSTMAA), C(11)H(14)BrNO(3)S, are trans to each other, similar to what is observed in N-(4-chloro­phenyl­sulfon­yl)-2,2,2-trimethyl­acet­amide (N4CPSTMAA) and 2,2,2-trimethyl-N-(4-methyl­phenyl­­sulfon­yl)acetamide (N4MPSTMAA). The bond para­meters in N4BPSTMAA are similar to those in N4CPSTMAA, N4MPSTMAA, N-aryl-2,2,2-trimethyl­acet­amides and 4-bromo­benzene­sulfonamide. The benzene ring and the SO(2)—NH—CO—C group in N4BPSTMAA form a dihedral angle of 82.8 (1)°, comparable with the values of 82.2 (1)° in N4CPSTMAA and 71.2 (1)° in N4MPSTMAA. N—H⋯O hydrogen bonds form a centrosymmetric ring characterized by an R (2) (2)(8) motif.
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spelling pubmed-29620222010-12-30 N-(4-Bromo­phenyl­sulfon­yl)-2,2,2-tri­methyl­acetamide Gowda, B. Thimme Foro, Sabine Nirmala, P. G. Sowmya, B. P. Fuess, Hartmut Acta Crystallogr Sect E Struct Rep Online Organic Papers The conformations of the N—H and C=O bonds in the SO(2)—NH—CO—C group of the title compound (N4BPSTMAA), C(11)H(14)BrNO(3)S, are trans to each other, similar to what is observed in N-(4-chloro­phenyl­sulfon­yl)-2,2,2-trimethyl­acet­amide (N4CPSTMAA) and 2,2,2-trimethyl-N-(4-methyl­phenyl­­sulfon­yl)acetamide (N4MPSTMAA). The bond para­meters in N4BPSTMAA are similar to those in N4CPSTMAA, N4MPSTMAA, N-aryl-2,2,2-trimethyl­acet­amides and 4-bromo­benzene­sulfonamide. The benzene ring and the SO(2)—NH—CO—C group in N4BPSTMAA form a dihedral angle of 82.8 (1)°, comparable with the values of 82.2 (1)° in N4CPSTMAA and 71.2 (1)° in N4MPSTMAA. N—H⋯O hydrogen bonds form a centrosymmetric ring characterized by an R (2) (2)(8) motif. International Union of Crystallography 2008-07-05 /pmc/articles/PMC2962022/ /pubmed/21203109 http://dx.doi.org/10.1107/S1600536808019375 Text en © Gowda et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gowda, B. Thimme
Foro, Sabine
Nirmala, P. G.
Sowmya, B. P.
Fuess, Hartmut
N-(4-Bromo­phenyl­sulfon­yl)-2,2,2-tri­methyl­acetamide
title N-(4-Bromo­phenyl­sulfon­yl)-2,2,2-tri­methyl­acetamide
title_full N-(4-Bromo­phenyl­sulfon­yl)-2,2,2-tri­methyl­acetamide
title_fullStr N-(4-Bromo­phenyl­sulfon­yl)-2,2,2-tri­methyl­acetamide
title_full_unstemmed N-(4-Bromo­phenyl­sulfon­yl)-2,2,2-tri­methyl­acetamide
title_short N-(4-Bromo­phenyl­sulfon­yl)-2,2,2-tri­methyl­acetamide
title_sort n-(4-bromo­phenyl­sulfon­yl)-2,2,2-tri­methyl­acetamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962022/
https://www.ncbi.nlm.nih.gov/pubmed/21203109
http://dx.doi.org/10.1107/S1600536808019375
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