9-(2-Pyridylmeth­oxy)-1,10-phenanthrolin-1-ium perchlorate methanol solvate

In the title organic salt, C(18)H(14)N(3)O(+)·ClO(4) (−)·CH(4)O, there is a π–π stacking inter­action between neighbouring 1,10-phenanthroline rings and the relevant distances are 3.5453 (18) Å for the centroid–centroid distance and 3.354 Å for the perpendicular distance. There is also a relatively...

Descripción completa

Detalles Bibliográficos
Autores principales: Zhang, Shi Guo, Hou, Chao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962027/
https://www.ncbi.nlm.nih.gov/pubmed/21203165
http://dx.doi.org/10.1107/S1600536808020606
_version_ 1782189123336929280
author Zhang, Shi Guo
Hou, Chao
author_facet Zhang, Shi Guo
Hou, Chao
author_sort Zhang, Shi Guo
collection PubMed
description In the title organic salt, C(18)H(14)N(3)O(+)·ClO(4) (−)·CH(4)O, there is a π–π stacking inter­action between neighbouring 1,10-phenanthroline rings and the relevant distances are 3.5453 (18) Å for the centroid–centroid distance and 3.354 Å for the perpendicular distance. There is also a relatively close contact between a C—H bond and a symmetry-related pyridine ring. There are classical N—H⋯O and O—H⋯N hydrogen bonds and non-classical C—H⋯O hydrogen bonds involving the cation, methanol solvent mol­ecule and perchlorate anion.
format Text
id pubmed-2962027
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29620272010-12-30 9-(2-Pyridylmeth­oxy)-1,10-phenanthrolin-1-ium perchlorate methanol solvate Zhang, Shi Guo Hou, Chao Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title organic salt, C(18)H(14)N(3)O(+)·ClO(4) (−)·CH(4)O, there is a π–π stacking inter­action between neighbouring 1,10-phenanthroline rings and the relevant distances are 3.5453 (18) Å for the centroid–centroid distance and 3.354 Å for the perpendicular distance. There is also a relatively close contact between a C—H bond and a symmetry-related pyridine ring. There are classical N—H⋯O and O—H⋯N hydrogen bonds and non-classical C—H⋯O hydrogen bonds involving the cation, methanol solvent mol­ecule and perchlorate anion. International Union of Crystallography 2008-07-09 /pmc/articles/PMC2962027/ /pubmed/21203165 http://dx.doi.org/10.1107/S1600536808020606 Text en © Zhang and Hou 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zhang, Shi Guo
Hou, Chao
9-(2-Pyridylmeth­oxy)-1,10-phenanthrolin-1-ium perchlorate methanol solvate
title 9-(2-Pyridylmeth­oxy)-1,10-phenanthrolin-1-ium perchlorate methanol solvate
title_full 9-(2-Pyridylmeth­oxy)-1,10-phenanthrolin-1-ium perchlorate methanol solvate
title_fullStr 9-(2-Pyridylmeth­oxy)-1,10-phenanthrolin-1-ium perchlorate methanol solvate
title_full_unstemmed 9-(2-Pyridylmeth­oxy)-1,10-phenanthrolin-1-ium perchlorate methanol solvate
title_short 9-(2-Pyridylmeth­oxy)-1,10-phenanthrolin-1-ium perchlorate methanol solvate
title_sort 9-(2-pyridylmeth­oxy)-1,10-phenanthrolin-1-ium perchlorate methanol solvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962027/
https://www.ncbi.nlm.nih.gov/pubmed/21203165
http://dx.doi.org/10.1107/S1600536808020606
work_keys_str_mv AT zhangshiguo 92pyridylmethoxy110phenanthrolin1iumperchloratemethanolsolvate
AT houchao 92pyridylmethoxy110phenanthrolin1iumperchloratemethanolsolvate

Ejemplares similares