Cargando…
2,5,7-Trimethyl-3-phenylsulfinyl-1-benzofuran
The title compound, C(17)H(16)O(2)S, was prepared by the oxidation of 2,5,7-trimethyl-3-phenylsulfanyl-1-benzofuran with 3-chloroperoxybenzoic acid. The O atom and the phenyl group of the phenylsulfinyl substituent lie on opposite sides of the plane of the benzofuran fragment. The phenyl ring is...
Autores principales: | , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962028/ https://www.ncbi.nlm.nih.gov/pubmed/21203115 http://dx.doi.org/10.1107/S1600536808019302 |
_version_ | 1782189123568664576 |
---|---|
author | Choi, Hong Dae Seo, Pil Ja Son, Byeng Wha Lee, Uk |
author_facet | Choi, Hong Dae Seo, Pil Ja Son, Byeng Wha Lee, Uk |
author_sort | Choi, Hong Dae |
collection | PubMed |
description | The title compound, C(17)H(16)O(2)S, was prepared by the oxidation of 2,5,7-trimethyl-3-phenylsulfanyl-1-benzofuran with 3-chloroperoxybenzoic acid. The O atom and the phenyl group of the phenylsulfinyl substituent lie on opposite sides of the plane of the benzofuran fragment. The phenyl ring is nearly perpendicular to the plane of the benzofuran unit [88.30 (9)°] and is tilted slightly towards it. No π–π or C—H⋯π interactions are observed between neighbouring molecules in the crystal structure because of steric hindrance induced by the three methyl groups. |
format | Text |
id | pubmed-2962028 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29620282010-12-30 2,5,7-Trimethyl-3-phenylsulfinyl-1-benzofuran Choi, Hong Dae Seo, Pil Ja Son, Byeng Wha Lee, Uk Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(17)H(16)O(2)S, was prepared by the oxidation of 2,5,7-trimethyl-3-phenylsulfanyl-1-benzofuran with 3-chloroperoxybenzoic acid. The O atom and the phenyl group of the phenylsulfinyl substituent lie on opposite sides of the plane of the benzofuran fragment. The phenyl ring is nearly perpendicular to the plane of the benzofuran unit [88.30 (9)°] and is tilted slightly towards it. No π–π or C—H⋯π interactions are observed between neighbouring molecules in the crystal structure because of steric hindrance induced by the three methyl groups. International Union of Crystallography 2008-07-05 /pmc/articles/PMC2962028/ /pubmed/21203115 http://dx.doi.org/10.1107/S1600536808019302 Text en © Choi et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Choi, Hong Dae Seo, Pil Ja Son, Byeng Wha Lee, Uk 2,5,7-Trimethyl-3-phenylsulfinyl-1-benzofuran |
title | 2,5,7-Trimethyl-3-phenylsulfinyl-1-benzofuran |
title_full | 2,5,7-Trimethyl-3-phenylsulfinyl-1-benzofuran |
title_fullStr | 2,5,7-Trimethyl-3-phenylsulfinyl-1-benzofuran |
title_full_unstemmed | 2,5,7-Trimethyl-3-phenylsulfinyl-1-benzofuran |
title_short | 2,5,7-Trimethyl-3-phenylsulfinyl-1-benzofuran |
title_sort | 2,5,7-trimethyl-3-phenylsulfinyl-1-benzofuran |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962028/ https://www.ncbi.nlm.nih.gov/pubmed/21203115 http://dx.doi.org/10.1107/S1600536808019302 |
work_keys_str_mv | AT choihongdae 257trimethyl3phenylsulfinyl1benzofuran AT seopilja 257trimethyl3phenylsulfinyl1benzofuran AT sonbyengwha 257trimethyl3phenylsulfinyl1benzofuran AT leeuk 257trimethyl3phenylsulfinyl1benzofuran |