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2,5,7-Trimethyl-3-phenyl­sulfinyl-1-benzo­furan

The title compound, C(17)H(16)O(2)S, was prepared by the oxidation of 2,5,7-trimethyl-3-phenyl­sulfanyl-1-benzofuran with 3-chloro­peroxy­benzoic acid. The O atom and the phenyl group of the phenyl­sulfinyl substituent lie on opposite sides of the plane of the benzofuran fragment. The phenyl ring is...

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Detalles Bibliográficos
Autores principales: Choi, Hong Dae, Seo, Pil Ja, Son, Byeng Wha, Lee, Uk
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962028/
https://www.ncbi.nlm.nih.gov/pubmed/21203115
http://dx.doi.org/10.1107/S1600536808019302
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author Choi, Hong Dae
Seo, Pil Ja
Son, Byeng Wha
Lee, Uk
author_facet Choi, Hong Dae
Seo, Pil Ja
Son, Byeng Wha
Lee, Uk
author_sort Choi, Hong Dae
collection PubMed
description The title compound, C(17)H(16)O(2)S, was prepared by the oxidation of 2,5,7-trimethyl-3-phenyl­sulfanyl-1-benzofuran with 3-chloro­peroxy­benzoic acid. The O atom and the phenyl group of the phenyl­sulfinyl substituent lie on opposite sides of the plane of the benzofuran fragment. The phenyl ring is nearly perpendicular to the plane of the benzofuran unit [88.30 (9)°] and is tilted slightly towards it. No π–π or C—H⋯π inter­actions are observed between neighbouring mol­ecules in the crystal structure because of steric hindrance induced by the three methyl groups.
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spelling pubmed-29620282010-12-30 2,5,7-Trimethyl-3-phenyl­sulfinyl-1-benzo­furan Choi, Hong Dae Seo, Pil Ja Son, Byeng Wha Lee, Uk Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(17)H(16)O(2)S, was prepared by the oxidation of 2,5,7-trimethyl-3-phenyl­sulfanyl-1-benzofuran with 3-chloro­peroxy­benzoic acid. The O atom and the phenyl group of the phenyl­sulfinyl substituent lie on opposite sides of the plane of the benzofuran fragment. The phenyl ring is nearly perpendicular to the plane of the benzofuran unit [88.30 (9)°] and is tilted slightly towards it. No π–π or C—H⋯π inter­actions are observed between neighbouring mol­ecules in the crystal structure because of steric hindrance induced by the three methyl groups. International Union of Crystallography 2008-07-05 /pmc/articles/PMC2962028/ /pubmed/21203115 http://dx.doi.org/10.1107/S1600536808019302 Text en © Choi et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Choi, Hong Dae
Seo, Pil Ja
Son, Byeng Wha
Lee, Uk
2,5,7-Trimethyl-3-phenyl­sulfinyl-1-benzo­furan
title 2,5,7-Trimethyl-3-phenyl­sulfinyl-1-benzo­furan
title_full 2,5,7-Trimethyl-3-phenyl­sulfinyl-1-benzo­furan
title_fullStr 2,5,7-Trimethyl-3-phenyl­sulfinyl-1-benzo­furan
title_full_unstemmed 2,5,7-Trimethyl-3-phenyl­sulfinyl-1-benzo­furan
title_short 2,5,7-Trimethyl-3-phenyl­sulfinyl-1-benzo­furan
title_sort 2,5,7-trimethyl-3-phenyl­sulfinyl-1-benzo­furan
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962028/
https://www.ncbi.nlm.nih.gov/pubmed/21203115
http://dx.doi.org/10.1107/S1600536808019302
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