Methyl N′-[(E)-4-hydr­oxy-3-methoxy­benzyl­idene]hydrazinecarboxyl­ate

The mol­ecule of the title compound, C(10)H(12)N(2)O(4), adopts a trans configuration with respect to the C=N double bond. The dihedral angle between the benzene ring and the hydrazinecarboxyl­ate mean plane is 36.54 (6)°. The mol­ecules are linked into a two-dimensional network by inter­molecular O...

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Detalles Bibliográficos
Autor principal: Cheng, Xiang-Wei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962030/
https://www.ncbi.nlm.nih.gov/pubmed/21203117
http://dx.doi.org/10.1107/S1600536808019788
Descripción
Sumario:The mol­ecule of the title compound, C(10)H(12)N(2)O(4), adopts a trans configuration with respect to the C=N double bond. The dihedral angle between the benzene ring and the hydrazinecarboxyl­ate mean plane is 36.54 (6)°. The mol­ecules are linked into a two-dimensional network by inter­molecular O—H⋯O, N—H⋯O and O—H⋯N hydrogen bonds, and by aromatic π–π stacking inter­actions [ring-centroid separation 3.7689 (9) Å].

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