Methyl N′-[(E)-4-hydr­oxy-3-methoxy­benzyl­idene]hydrazinecarboxyl­ate

The mol­ecule of the title compound, C(10)H(12)N(2)O(4), adopts a trans configuration with respect to the C=N double bond. The dihedral angle between the benzene ring and the hydrazinecarboxyl­ate mean plane is 36.54 (6)°. The mol­ecules are linked into a two-dimensional network by inter­molecular O...

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Autor principal: Cheng, Xiang-Wei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962030/
https://www.ncbi.nlm.nih.gov/pubmed/21203117
http://dx.doi.org/10.1107/S1600536808019788
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author Cheng, Xiang-Wei
author_facet Cheng, Xiang-Wei
author_sort Cheng, Xiang-Wei
collection PubMed
description The mol­ecule of the title compound, C(10)H(12)N(2)O(4), adopts a trans configuration with respect to the C=N double bond. The dihedral angle between the benzene ring and the hydrazinecarboxyl­ate mean plane is 36.54 (6)°. The mol­ecules are linked into a two-dimensional network by inter­molecular O—H⋯O, N—H⋯O and O—H⋯N hydrogen bonds, and by aromatic π–π stacking inter­actions [ring-centroid separation 3.7689 (9) Å].
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spelling pubmed-29620302010-12-30 Methyl N′-[(E)-4-hydr­oxy-3-methoxy­benzyl­idene]hydrazinecarboxyl­ate Cheng, Xiang-Wei Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecule of the title compound, C(10)H(12)N(2)O(4), adopts a trans configuration with respect to the C=N double bond. The dihedral angle between the benzene ring and the hydrazinecarboxyl­ate mean plane is 36.54 (6)°. The mol­ecules are linked into a two-dimensional network by inter­molecular O—H⋯O, N—H⋯O and O—H⋯N hydrogen bonds, and by aromatic π–π stacking inter­actions [ring-centroid separation 3.7689 (9) Å]. International Union of Crystallography 2008-07-05 /pmc/articles/PMC2962030/ /pubmed/21203117 http://dx.doi.org/10.1107/S1600536808019788 Text en © Xiang-Wei Cheng 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Cheng, Xiang-Wei
Methyl N′-[(E)-4-hydr­oxy-3-methoxy­benzyl­idene]hydrazinecarboxyl­ate
title Methyl N′-[(E)-4-hydr­oxy-3-methoxy­benzyl­idene]hydrazinecarboxyl­ate
title_full Methyl N′-[(E)-4-hydr­oxy-3-methoxy­benzyl­idene]hydrazinecarboxyl­ate
title_fullStr Methyl N′-[(E)-4-hydr­oxy-3-methoxy­benzyl­idene]hydrazinecarboxyl­ate
title_full_unstemmed Methyl N′-[(E)-4-hydr­oxy-3-methoxy­benzyl­idene]hydrazinecarboxyl­ate
title_short Methyl N′-[(E)-4-hydr­oxy-3-methoxy­benzyl­idene]hydrazinecarboxyl­ate
title_sort methyl n′-[(e)-4-hydr­oxy-3-methoxy­benzyl­idene]hydrazinecarboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962030/
https://www.ncbi.nlm.nih.gov/pubmed/21203117
http://dx.doi.org/10.1107/S1600536808019788
work_keys_str_mv AT chengxiangwei methylne4hydroxy3methoxybenzylidenehydrazinecarboxylate

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