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3-Ethyl-4-[(E)-2-methyl­benzyl­idene­amino]-1H-1,2,4-triazole-5(4H)-thione

Crystals of the title compound, C(12)H(14)N(4)S, were obtained from a condensation reaction of 4-amino-3-ethyl-1H-1,2,4-triazole-5(4H)-thione and 2-methyl­benzaldehyde. In the mol­ecular structure, there is a short N=C double bond [1.255 (2) Å], and the benzene and triazole rings are located on oppo...

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Detalles Bibliográficos
Autores principales: Wang, Shan-Heng, Xu, Ying-Li, Xie, Pei-Jin, Wang, Wen-Long, Shan, Shang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962033/
https://www.ncbi.nlm.nih.gov/pubmed/21203120
http://dx.doi.org/10.1107/S1600536808019867
Descripción
Sumario:Crystals of the title compound, C(12)H(14)N(4)S, were obtained from a condensation reaction of 4-amino-3-ethyl-1H-1,2,4-triazole-5(4H)-thione and 2-methyl­benzaldehyde. In the mol­ecular structure, there is a short N=C double bond [1.255 (2) Å], and the benzene and triazole rings are located on opposite sites of this double bond. The two rings are approximately parallel to each other, the dihedral angle being 1.75 (11)°. A partially overlapped arrangement is observed between the nearly parallel triazole and benzene rings of adjacent mol­ecules; the perpendicular distance of the centroid of the triazole ring from the benzene ring is 3.482 Å, indicating the existence of π–π stacking in the crystal structure.