N-[(5-Chloro-3-methyl-1-phenyl-1H-pyrazol-4-yl)carbon­yl]-N′-(4-hydroxy­phen­yl)thio­urea

In the title compound, C(18)H(15)ClN(4)O(2)S, the pyrazole ring makes dihedral angles of 67.4 (1) and 12.5 (1)° with the phenyl and 4-hydroxy­phenyl groups, respectively; the two benzene rings are twisted by 60.1 (1)° with respect to each other. The thio­urea NH groups are involved in N—H⋯O and N—H⋯...

Descripción completa

Detalles Bibliográficos
Autores principales: Du, Haitang, Du, Haijun, An, Ying, Li, Shengnan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962037/
https://www.ncbi.nlm.nih.gov/pubmed/21203124
http://dx.doi.org/10.1107/S1600536808019417
_version_ 1782189125676302336
author Du, Haitang
Du, Haijun
An, Ying
Li, Shengnan
author_facet Du, Haitang
Du, Haijun
An, Ying
Li, Shengnan
author_sort Du, Haitang
collection PubMed
description In the title compound, C(18)H(15)ClN(4)O(2)S, the pyrazole ring makes dihedral angles of 67.4 (1) and 12.5 (1)° with the phenyl and 4-hydroxy­phenyl groups, respectively; the two benzene rings are twisted by 60.1 (1)° with respect to each other. The thio­urea NH groups are involved in N—H⋯O and N—H⋯Cl intra­molecular hydrogen bonds. A hydrogen bond between the phenolic OH group and the pyrazole N atom connects mol­ecules into a one-dimensional polymeric structure.
format Text
id pubmed-2962037
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29620372010-12-30 N-[(5-Chloro-3-methyl-1-phenyl-1H-pyrazol-4-yl)carbon­yl]-N′-(4-hydroxy­phen­yl)thio­urea Du, Haitang Du, Haijun An, Ying Li, Shengnan Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(18)H(15)ClN(4)O(2)S, the pyrazole ring makes dihedral angles of 67.4 (1) and 12.5 (1)° with the phenyl and 4-hydroxy­phenyl groups, respectively; the two benzene rings are twisted by 60.1 (1)° with respect to each other. The thio­urea NH groups are involved in N—H⋯O and N—H⋯Cl intra­molecular hydrogen bonds. A hydrogen bond between the phenolic OH group and the pyrazole N atom connects mol­ecules into a one-dimensional polymeric structure. International Union of Crystallography 2008-07-05 /pmc/articles/PMC2962037/ /pubmed/21203124 http://dx.doi.org/10.1107/S1600536808019417 Text en © Du et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Du, Haitang
Du, Haijun
An, Ying
Li, Shengnan
N-[(5-Chloro-3-methyl-1-phenyl-1H-pyrazol-4-yl)carbon­yl]-N′-(4-hydroxy­phen­yl)thio­urea
title N-[(5-Chloro-3-methyl-1-phenyl-1H-pyrazol-4-yl)carbon­yl]-N′-(4-hydroxy­phen­yl)thio­urea
title_full N-[(5-Chloro-3-methyl-1-phenyl-1H-pyrazol-4-yl)carbon­yl]-N′-(4-hydroxy­phen­yl)thio­urea
title_fullStr N-[(5-Chloro-3-methyl-1-phenyl-1H-pyrazol-4-yl)carbon­yl]-N′-(4-hydroxy­phen­yl)thio­urea
title_full_unstemmed N-[(5-Chloro-3-methyl-1-phenyl-1H-pyrazol-4-yl)carbon­yl]-N′-(4-hydroxy­phen­yl)thio­urea
title_short N-[(5-Chloro-3-methyl-1-phenyl-1H-pyrazol-4-yl)carbon­yl]-N′-(4-hydroxy­phen­yl)thio­urea
title_sort n-[(5-chloro-3-methyl-1-phenyl-1h-pyrazol-4-yl)carbon­yl]-n′-(4-hydroxy­phen­yl)thio­urea
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962037/
https://www.ncbi.nlm.nih.gov/pubmed/21203124
http://dx.doi.org/10.1107/S1600536808019417
work_keys_str_mv AT duhaitang n5chloro3methyl1phenyl1hpyrazol4ylcarbonyln4hydroxyphenylthiourea
AT duhaijun n5chloro3methyl1phenyl1hpyrazol4ylcarbonyln4hydroxyphenylthiourea
AT anying n5chloro3methyl1phenyl1hpyrazol4ylcarbonyln4hydroxyphenylthiourea
AT lishengnan n5chloro3methyl1phenyl1hpyrazol4ylcarbonyln4hydroxyphenylthiourea

Ejemplares similares