Di-tert-butyl 2,2′-(biphenyl-2,2′-diyl­dioxy)diacetate

The title compound, C(24)H(30)O(6), does not exhibit π–π inter­actions due to the steric effect of the bulky tert-butyl groups present in the mol­ecule. The presence of these groups at the 2 and 2′ positions hinders the free motion of the benzene rings relative to each other, causing them to adopt a...

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Detalles Bibliográficos
Autores principales: Ali, Qamar, Ibad, Farooq, Shah, Muhammad Raza, VanDerveer, Donald
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962041/
https://www.ncbi.nlm.nih.gov/pubmed/21203128
http://dx.doi.org/10.1107/S1600536808019764
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author Ali, Qamar
Ibad, Farooq
Shah, Muhammad Raza
VanDerveer, Donald
author_facet Ali, Qamar
Ibad, Farooq
Shah, Muhammad Raza
VanDerveer, Donald
author_sort Ali, Qamar
collection PubMed
description The title compound, C(24)H(30)O(6), does not exhibit π–π inter­actions due to the steric effect of the bulky tert-butyl groups present in the mol­ecule. The presence of these groups at the 2 and 2′ positions hinders the free motion of the benzene rings relative to each other, causing them to adopt an anti­periplanar arrangement. The benzene rings are twisted by just under 50.96 (17)° with respect to each other. The carbonyl groups within the mol­ecule are directed in different directions, one towards the biphenyl group and the other away from it. The mol­ecules are linked together by C=O⋯H—C hydrogen bonds.
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spelling pubmed-29620412010-12-30 Di-tert-butyl 2,2′-(biphenyl-2,2′-diyl­dioxy)diacetate Ali, Qamar Ibad, Farooq Shah, Muhammad Raza VanDerveer, Donald Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(24)H(30)O(6), does not exhibit π–π inter­actions due to the steric effect of the bulky tert-butyl groups present in the mol­ecule. The presence of these groups at the 2 and 2′ positions hinders the free motion of the benzene rings relative to each other, causing them to adopt an anti­periplanar arrangement. The benzene rings are twisted by just under 50.96 (17)° with respect to each other. The carbonyl groups within the mol­ecule are directed in different directions, one towards the biphenyl group and the other away from it. The mol­ecules are linked together by C=O⋯H—C hydrogen bonds. International Union of Crystallography 2008-07-05 /pmc/articles/PMC2962041/ /pubmed/21203128 http://dx.doi.org/10.1107/S1600536808019764 Text en © Ali et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ali, Qamar
Ibad, Farooq
Shah, Muhammad Raza
VanDerveer, Donald
Di-tert-butyl 2,2′-(biphenyl-2,2′-diyl­dioxy)diacetate
title Di-tert-butyl 2,2′-(biphenyl-2,2′-diyl­dioxy)diacetate
title_full Di-tert-butyl 2,2′-(biphenyl-2,2′-diyl­dioxy)diacetate
title_fullStr Di-tert-butyl 2,2′-(biphenyl-2,2′-diyl­dioxy)diacetate
title_full_unstemmed Di-tert-butyl 2,2′-(biphenyl-2,2′-diyl­dioxy)diacetate
title_short Di-tert-butyl 2,2′-(biphenyl-2,2′-diyl­dioxy)diacetate
title_sort di-tert-butyl 2,2′-(biphenyl-2,2′-diyl­dioxy)diacetate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962041/
https://www.ncbi.nlm.nih.gov/pubmed/21203128
http://dx.doi.org/10.1107/S1600536808019764
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AT shahmuhammadraza ditertbutyl22biphenyl22diyldioxydiacetate
AT vanderveerdonald ditertbutyl22biphenyl22diyldioxydiacetate

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