1-(2-Furo­yl)-3-(o-tol­yl)thio­urea

The title compound, C(13)H(12)N(2)O(2)S, was synthesized from furoyl isothio­cyanate and o-toluidine in dry acetone. The thio­urea group is in the thio­amide form. The central thio­urea fragment makes dihedral angles of 2.6 (1) and 22.4 (1)° with the ketofuran group and the benzene ring, respectivel...

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Detalles Bibliográficos
Autores principales: Corrêa, Rodrigo S., Estévez-Hernández, O., Ellena, J., Duque, J.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962048/
https://www.ncbi.nlm.nih.gov/pubmed/21203133
http://dx.doi.org/10.1107/S1600536808020114
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author Corrêa, Rodrigo S.
Estévez-Hernández, O.
Ellena, J.
Duque, J.
author_facet Corrêa, Rodrigo S.
Estévez-Hernández, O.
Ellena, J.
Duque, J.
author_sort Corrêa, Rodrigo S.
collection PubMed
description The title compound, C(13)H(12)N(2)O(2)S, was synthesized from furoyl isothio­cyanate and o-toluidine in dry acetone. The thio­urea group is in the thio­amide form. The central thio­urea fragment makes dihedral angles of 2.6 (1) and 22.4 (1)° with the ketofuran group and the benzene ring, respectively. The mol­ecular structure is stabilized by N—H⋯O hydrogen bonds. In the crystal structure, centrosymmetrically related mol­ecules are linked by a pair of N—H⋯S hydrogen bonds to form a dimer with an R (2) (2)(6) ring motif.
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spelling pubmed-29620482010-12-30 1-(2-Furo­yl)-3-(o-tol­yl)thio­urea Corrêa, Rodrigo S. Estévez-Hernández, O. Ellena, J. Duque, J. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(13)H(12)N(2)O(2)S, was synthesized from furoyl isothio­cyanate and o-toluidine in dry acetone. The thio­urea group is in the thio­amide form. The central thio­urea fragment makes dihedral angles of 2.6 (1) and 22.4 (1)° with the ketofuran group and the benzene ring, respectively. The mol­ecular structure is stabilized by N—H⋯O hydrogen bonds. In the crystal structure, centrosymmetrically related mol­ecules are linked by a pair of N—H⋯S hydrogen bonds to form a dimer with an R (2) (2)(6) ring motif. International Union of Crystallography 2008-07-05 /pmc/articles/PMC2962048/ /pubmed/21203133 http://dx.doi.org/10.1107/S1600536808020114 Text en © Corrêa et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Corrêa, Rodrigo S.
Estévez-Hernández, O.
Ellena, J.
Duque, J.
1-(2-Furo­yl)-3-(o-tol­yl)thio­urea
title 1-(2-Furo­yl)-3-(o-tol­yl)thio­urea
title_full 1-(2-Furo­yl)-3-(o-tol­yl)thio­urea
title_fullStr 1-(2-Furo­yl)-3-(o-tol­yl)thio­urea
title_full_unstemmed 1-(2-Furo­yl)-3-(o-tol­yl)thio­urea
title_short 1-(2-Furo­yl)-3-(o-tol­yl)thio­urea
title_sort 1-(2-furo­yl)-3-(o-tol­yl)thio­urea
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962048/
https://www.ncbi.nlm.nih.gov/pubmed/21203133
http://dx.doi.org/10.1107/S1600536808020114
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AT estevezhernandezo 12furoyl3otolylthiourea
AT ellenaj 12furoyl3otolylthiourea
AT duquej 12furoyl3otolylthiourea

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