Cargando…
1,4-Diazoniabicyclo[2.2.2]octane bis(2-chlorobenzoate)
The title compound, C(6)H(14)N(2) (2+)·2C(7)H(4)ClO(2) (−), contains trimeric units linked by N—H⋯O hydrogen bonds. The carboxylate groups of the 2-chlorobenzoate anions form dihedral angles of 66.1 (1) and 76.1 (1)° with the respective chlorobenzene rings to which they are bound. The hydrogen-bo...
Autores principales: | , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962050/ https://www.ncbi.nlm.nih.gov/pubmed/21203135 http://dx.doi.org/10.1107/S1600536808020096 |
Sumario: | The title compound, C(6)H(14)N(2) (2+)·2C(7)H(4)ClO(2) (−), contains trimeric units linked by N—H⋯O hydrogen bonds. The carboxylate groups of the 2-chlorobenzoate anions form dihedral angles of 66.1 (1) and 76.1 (1)° with the respective chlorobenzene rings to which they are bound. The hydrogen-bonded trimers are arranged in layers in the (200) planes and the chlorobenzoate anions form edge-to-face interactions between layers, with dihedral angles of 61.9 (1) and 49.8 (1)° and centroid–centroid distances of 4.85 (1) and 4.65 (1) Å, respectively, for two crystallographically distinct interactions. |
---|