1,4-Diazo­niabicyclo­[2.2.2]octane bis­(2-chloro­benzoate)

The title compound, C(6)H(14)N(2) (2+)·2C(7)H(4)ClO(2) (−), contains trimeric units linked by N—H⋯O hydrogen bonds. The carboxyl­ate groups of the 2-chloro­benzoate anions form dihedral angles of 66.1 (1) and 76.1 (1)° with the respective chloro­benzene rings to which they are bound. The hydrogen-bo...

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Detalles Bibliográficos
Autores principales: Skovsgaard, Signe, Bond, Andrew D.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962050/
https://www.ncbi.nlm.nih.gov/pubmed/21203135
http://dx.doi.org/10.1107/S1600536808020096
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author Skovsgaard, Signe
Bond, Andrew D.
author_facet Skovsgaard, Signe
Bond, Andrew D.
author_sort Skovsgaard, Signe
collection PubMed
description The title compound, C(6)H(14)N(2) (2+)·2C(7)H(4)ClO(2) (−), contains trimeric units linked by N—H⋯O hydrogen bonds. The carboxyl­ate groups of the 2-chloro­benzoate anions form dihedral angles of 66.1 (1) and 76.1 (1)° with the respective chloro­benzene rings to which they are bound. The hydrogen-bonded trimers are arranged in layers in the (200) planes and the chloro­benzoate anions form edge-to-face inter­actions between layers, with dihedral angles of 61.9 (1) and 49.8 (1)° and centroid–centroid distances of 4.85 (1) and 4.65 (1) Å, respectively, for two crystallographically distinct inter­actions.
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spelling pubmed-29620502010-12-30 1,4-Diazo­niabicyclo­[2.2.2]octane bis­(2-chloro­benzoate) Skovsgaard, Signe Bond, Andrew D. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(6)H(14)N(2) (2+)·2C(7)H(4)ClO(2) (−), contains trimeric units linked by N—H⋯O hydrogen bonds. The carboxyl­ate groups of the 2-chloro­benzoate anions form dihedral angles of 66.1 (1) and 76.1 (1)° with the respective chloro­benzene rings to which they are bound. The hydrogen-bonded trimers are arranged in layers in the (200) planes and the chloro­benzoate anions form edge-to-face inter­actions between layers, with dihedral angles of 61.9 (1) and 49.8 (1)° and centroid–centroid distances of 4.85 (1) and 4.65 (1) Å, respectively, for two crystallographically distinct inter­actions. International Union of Crystallography 2008-07-05 /pmc/articles/PMC2962050/ /pubmed/21203135 http://dx.doi.org/10.1107/S1600536808020096 Text en © Skovsgaard and Bond 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Skovsgaard, Signe
Bond, Andrew D.
1,4-Diazo­niabicyclo­[2.2.2]octane bis­(2-chloro­benzoate)
title 1,4-Diazo­niabicyclo­[2.2.2]octane bis­(2-chloro­benzoate)
title_full 1,4-Diazo­niabicyclo­[2.2.2]octane bis­(2-chloro­benzoate)
title_fullStr 1,4-Diazo­niabicyclo­[2.2.2]octane bis­(2-chloro­benzoate)
title_full_unstemmed 1,4-Diazo­niabicyclo­[2.2.2]octane bis­(2-chloro­benzoate)
title_short 1,4-Diazo­niabicyclo­[2.2.2]octane bis­(2-chloro­benzoate)
title_sort 1,4-diazo­niabicyclo­[2.2.2]octane bis­(2-chloro­benzoate)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962050/
https://www.ncbi.nlm.nih.gov/pubmed/21203135
http://dx.doi.org/10.1107/S1600536808020096
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AT bondandrewd 14diazoniabicyclo222octanebis2chlorobenzoate

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