Cargando…

X-ray crystal and computational structural study of (E)-2-[(2-chloro­phenyl)­iminometh­yl]-4-methoxy­phenol

In the mol­ecule of the title compound, C(14)H(12)ClNO, the two aromatic rings are oriented at a dihedral angle of 12.28 (7)°. An intra­molecular O—H⋯N hydrogen bond results in the formation of a nearly planar six-membered ring, which is oriented with respect to the aromatic rings at dihedral angles...

Descripción completa

Detalles Bibliográficos
Autores principales: Özek, Arzu, Büyükgüngör, Orhan, Albayrak, Çiğdem, Odabaşoğlu, Mustafa
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962062/
https://www.ncbi.nlm.nih.gov/pubmed/21203278
http://dx.doi.org/10.1107/S1600536808021958
_version_ 1782189131285135360
author Özek, Arzu
Büyükgüngör, Orhan
Albayrak, Çiğdem
Odabaşoğlu, Mustafa
author_facet Özek, Arzu
Büyükgüngör, Orhan
Albayrak, Çiğdem
Odabaşoğlu, Mustafa
author_sort Özek, Arzu
collection PubMed
description In the mol­ecule of the title compound, C(14)H(12)ClNO, the two aromatic rings are oriented at a dihedral angle of 12.28 (7)°. An intra­molecular O—H⋯N hydrogen bond results in the formation of a nearly planar six-membered ring, which is oriented with respect to the aromatic rings at dihedral angles of 0.18 (5) and 12.10 (6)°. In the crystal structure, weak inter­molecular C—H⋯O hydrogen bonds link the mol­ecules into chains along the c axis. There is a C—H⋯π contact between the methyl group and the chloro­phenyl ring and a π–π contact between the two benzene rings [centroid–centroid distance = 3.866 (1) Å].
format Text
id pubmed-2962062
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29620622010-12-30 X-ray crystal and computational structural study of (E)-2-[(2-chloro­phenyl)­iminometh­yl]-4-methoxy­phenol Özek, Arzu Büyükgüngör, Orhan Albayrak, Çiğdem Odabaşoğlu, Mustafa Acta Crystallogr Sect E Struct Rep Online Organic Papers In the mol­ecule of the title compound, C(14)H(12)ClNO, the two aromatic rings are oriented at a dihedral angle of 12.28 (7)°. An intra­molecular O—H⋯N hydrogen bond results in the formation of a nearly planar six-membered ring, which is oriented with respect to the aromatic rings at dihedral angles of 0.18 (5) and 12.10 (6)°. In the crystal structure, weak inter­molecular C—H⋯O hydrogen bonds link the mol­ecules into chains along the c axis. There is a C—H⋯π contact between the methyl group and the chloro­phenyl ring and a π–π contact between the two benzene rings [centroid–centroid distance = 3.866 (1) Å]. International Union of Crystallography 2008-07-23 /pmc/articles/PMC2962062/ /pubmed/21203278 http://dx.doi.org/10.1107/S1600536808021958 Text en © Özek et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Özek, Arzu
Büyükgüngör, Orhan
Albayrak, Çiğdem
Odabaşoğlu, Mustafa
X-ray crystal and computational structural study of (E)-2-[(2-chloro­phenyl)­iminometh­yl]-4-methoxy­phenol
title X-ray crystal and computational structural study of (E)-2-[(2-chloro­phenyl)­iminometh­yl]-4-methoxy­phenol
title_full X-ray crystal and computational structural study of (E)-2-[(2-chloro­phenyl)­iminometh­yl]-4-methoxy­phenol
title_fullStr X-ray crystal and computational structural study of (E)-2-[(2-chloro­phenyl)­iminometh­yl]-4-methoxy­phenol
title_full_unstemmed X-ray crystal and computational structural study of (E)-2-[(2-chloro­phenyl)­iminometh­yl]-4-methoxy­phenol
title_short X-ray crystal and computational structural study of (E)-2-[(2-chloro­phenyl)­iminometh­yl]-4-methoxy­phenol
title_sort x-ray crystal and computational structural study of (e)-2-[(2-chloro­phenyl)­iminometh­yl]-4-methoxy­phenol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962062/
https://www.ncbi.nlm.nih.gov/pubmed/21203278
http://dx.doi.org/10.1107/S1600536808021958
work_keys_str_mv AT ozekarzu xraycrystalandcomputationalstructuralstudyofe22chlorophenyliminomethyl4methoxyphenol
AT buyukgungororhan xraycrystalandcomputationalstructuralstudyofe22chlorophenyliminomethyl4methoxyphenol
AT albayrakcigdem xraycrystalandcomputationalstructuralstudyofe22chlorophenyliminomethyl4methoxyphenol
AT odabasoglumustafa xraycrystalandcomputationalstructuralstudyofe22chlorophenyliminomethyl4methoxyphenol