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1-[2-(2,6-Dichlorobenzyloxy)-2-(2-furyl)ethyl]-1H-benzimidazole
In the molecule of the title compound, C(20)H(16)Cl(2)N(2)O(2), the planar benzimidazole ring system is oriented with respect to the furan and dichlorobenzene rings at dihedral angles of 53.39 (6) and 31.04 (5)°, respectively. In the crystal structure, intermolecular C—H⋯Cl hydrogen bonds link th...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962068/ https://www.ncbi.nlm.nih.gov/pubmed/21203152 http://dx.doi.org/10.1107/S1600536808020758 |
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author | Özel Güven, Özden Erdoğan, Taner Coles, Simon J. Hökelek, Tuncer |
author_facet | Özel Güven, Özden Erdoğan, Taner Coles, Simon J. Hökelek, Tuncer |
author_sort | Özel Güven, Özden |
collection | PubMed |
description | In the molecule of the title compound, C(20)H(16)Cl(2)N(2)O(2), the planar benzimidazole ring system is oriented with respect to the furan and dichlorobenzene rings at dihedral angles of 53.39 (6) and 31.04 (5)°, respectively. In the crystal structure, intermolecular C—H⋯Cl hydrogen bonds link the molecules into centrosymmetric R (2) (2)(8) dimers. These dimers are connected via a C—H⋯π contact between the benzimidazole and the furan rings, and π–π contacts between the benzimidazole and dichlorobenzene ring systems [centroid–centroid distances = 3.505 (1), 3.567 (1), 3.505 (1) and 3.567 (1) Å]. |
format | Text |
id | pubmed-2962068 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29620682010-12-30 1-[2-(2,6-Dichlorobenzyloxy)-2-(2-furyl)ethyl]-1H-benzimidazole Özel Güven, Özden Erdoğan, Taner Coles, Simon J. Hökelek, Tuncer Acta Crystallogr Sect E Struct Rep Online Organic Papers In the molecule of the title compound, C(20)H(16)Cl(2)N(2)O(2), the planar benzimidazole ring system is oriented with respect to the furan and dichlorobenzene rings at dihedral angles of 53.39 (6) and 31.04 (5)°, respectively. In the crystal structure, intermolecular C—H⋯Cl hydrogen bonds link the molecules into centrosymmetric R (2) (2)(8) dimers. These dimers are connected via a C—H⋯π contact between the benzimidazole and the furan rings, and π–π contacts between the benzimidazole and dichlorobenzene ring systems [centroid–centroid distances = 3.505 (1), 3.567 (1), 3.505 (1) and 3.567 (1) Å]. International Union of Crystallography 2008-07-09 /pmc/articles/PMC2962068/ /pubmed/21203152 http://dx.doi.org/10.1107/S1600536808020758 Text en © Özel Güven et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Özel Güven, Özden Erdoğan, Taner Coles, Simon J. Hökelek, Tuncer 1-[2-(2,6-Dichlorobenzyloxy)-2-(2-furyl)ethyl]-1H-benzimidazole |
title | 1-[2-(2,6-Dichlorobenzyloxy)-2-(2-furyl)ethyl]-1H-benzimidazole |
title_full | 1-[2-(2,6-Dichlorobenzyloxy)-2-(2-furyl)ethyl]-1H-benzimidazole |
title_fullStr | 1-[2-(2,6-Dichlorobenzyloxy)-2-(2-furyl)ethyl]-1H-benzimidazole |
title_full_unstemmed | 1-[2-(2,6-Dichlorobenzyloxy)-2-(2-furyl)ethyl]-1H-benzimidazole |
title_short | 1-[2-(2,6-Dichlorobenzyloxy)-2-(2-furyl)ethyl]-1H-benzimidazole |
title_sort | 1-[2-(2,6-dichlorobenzyloxy)-2-(2-furyl)ethyl]-1h-benzimidazole |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962068/ https://www.ncbi.nlm.nih.gov/pubmed/21203152 http://dx.doi.org/10.1107/S1600536808020758 |
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