N′-(2,4-Dinitro­phen­yl)acetohydrazide

In the title compound, C(8)H(8)N(4)O(5), the nitro groups ortho and para to the hydrazone group are twisted by 10.0 (2) and 3.6 (2)°, respectively, relative to the aromatic ring. The structure exhibits an intra­molecular N—H⋯O hydrogen bond between the hydrazide and ortho-nitro groups. There is a st...

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Autores principales: Zia-ur-Rehman, Muhammad, Elsegood, Mark R. J., Mahmud, Shahid, Siddiqui, Hamid Latif
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962072/
https://www.ncbi.nlm.nih.gov/pubmed/21203156
http://dx.doi.org/10.1107/S1600536808019685
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author Zia-ur-Rehman, Muhammad
Elsegood, Mark R. J.
Mahmud, Shahid
Siddiqui, Hamid Latif
author_facet Zia-ur-Rehman, Muhammad
Elsegood, Mark R. J.
Mahmud, Shahid
Siddiqui, Hamid Latif
author_sort Zia-ur-Rehman, Muhammad
collection PubMed
description In the title compound, C(8)H(8)N(4)O(5), the nitro groups ortho and para to the hydrazone group are twisted by 10.0 (2) and 3.6 (2)°, respectively, relative to the aromatic ring. The structure exhibits an intra­molecular N—H⋯O hydrogen bond between the hydrazide and ortho-nitro groups. There is a strong inter­molecular C=O⋯H—N hydrogen bond, giving rise to chains, and weaker ONO⋯NO(2) [2.944 (2) Å] and C—H⋯O—N inter­actions linking the mol­ecules into a three-dimensional network.
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spelling pubmed-29620722010-12-30 N′-(2,4-Dinitro­phen­yl)acetohydrazide Zia-ur-Rehman, Muhammad Elsegood, Mark R. J. Mahmud, Shahid Siddiqui, Hamid Latif Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(8)H(8)N(4)O(5), the nitro groups ortho and para to the hydrazone group are twisted by 10.0 (2) and 3.6 (2)°, respectively, relative to the aromatic ring. The structure exhibits an intra­molecular N—H⋯O hydrogen bond between the hydrazide and ortho-nitro groups. There is a strong inter­molecular C=O⋯H—N hydrogen bond, giving rise to chains, and weaker ONO⋯NO(2) [2.944 (2) Å] and C—H⋯O—N inter­actions linking the mol­ecules into a three-dimensional network. International Union of Crystallography 2008-07-09 /pmc/articles/PMC2962072/ /pubmed/21203156 http://dx.doi.org/10.1107/S1600536808019685 Text en © Zia-ur-Rehman et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zia-ur-Rehman, Muhammad
Elsegood, Mark R. J.
Mahmud, Shahid
Siddiqui, Hamid Latif
N′-(2,4-Dinitro­phen­yl)acetohydrazide
title N′-(2,4-Dinitro­phen­yl)acetohydrazide
title_full N′-(2,4-Dinitro­phen­yl)acetohydrazide
title_fullStr N′-(2,4-Dinitro­phen­yl)acetohydrazide
title_full_unstemmed N′-(2,4-Dinitro­phen­yl)acetohydrazide
title_short N′-(2,4-Dinitro­phen­yl)acetohydrazide
title_sort n′-(2,4-dinitro­phen­yl)acetohydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962072/
https://www.ncbi.nlm.nih.gov/pubmed/21203156
http://dx.doi.org/10.1107/S1600536808019685
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AT elsegoodmarkrj n24dinitrophenylacetohydrazide
AT mahmudshahid n24dinitrophenylacetohydrazide
AT siddiquihamidlatif n24dinitrophenylacetohydrazide

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