A monoclinic polymorph of N,N′-bis­(2,6-diisopropyl­phen­yl)formamidine

A new polymorph of N,N′-bis­(2,6-diisopropyl­phen­yl)formamidine, C(25)H(36)N(2), is reported, which is different from the previously reported ortho­rhom­bic structure. The mol­ecule crystallizes in the E–anti configuration, with tautomeric disorder of the N-bonded H atoms and no clear distinction b...

Descripción completa

Detalles Bibliográficos
Autor principal: Masuda, Jason D.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962078/
https://www.ncbi.nlm.nih.gov/pubmed/21203162
http://dx.doi.org/10.1107/S160053680802076X
_version_ 1782189135017017344
author Masuda, Jason D.
author_facet Masuda, Jason D.
author_sort Masuda, Jason D.
collection PubMed
description A new polymorph of N,N′-bis­(2,6-diisopropyl­phen­yl)formamidine, C(25)H(36)N(2), is reported, which is different from the previously reported ortho­rhom­bic structure. The mol­ecule crystallizes in the E–anti configuration, with tautomeric disorder of the N-bonded H atoms and no clear distinction between imine and amine functionalities. The mol­ecules form hydrogen-bonded dimers with inter­molecular N⋯N distances shorter than those in the ortho­rhom­bic polymorph.
format Text
id pubmed-2962078
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29620782010-12-30 A monoclinic polymorph of N,N′-bis­(2,6-diisopropyl­phen­yl)formamidine Masuda, Jason D. Acta Crystallogr Sect E Struct Rep Online Organic Papers A new polymorph of N,N′-bis­(2,6-diisopropyl­phen­yl)formamidine, C(25)H(36)N(2), is reported, which is different from the previously reported ortho­rhom­bic structure. The mol­ecule crystallizes in the E–anti configuration, with tautomeric disorder of the N-bonded H atoms and no clear distinction between imine and amine functionalities. The mol­ecules form hydrogen-bonded dimers with inter­molecular N⋯N distances shorter than those in the ortho­rhom­bic polymorph. International Union of Crystallography 2008-07-09 /pmc/articles/PMC2962078/ /pubmed/21203162 http://dx.doi.org/10.1107/S160053680802076X Text en © Jason D. Masuda 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Masuda, Jason D.
A monoclinic polymorph of N,N′-bis­(2,6-diisopropyl­phen­yl)formamidine
title A monoclinic polymorph of N,N′-bis­(2,6-diisopropyl­phen­yl)formamidine
title_full A monoclinic polymorph of N,N′-bis­(2,6-diisopropyl­phen­yl)formamidine
title_fullStr A monoclinic polymorph of N,N′-bis­(2,6-diisopropyl­phen­yl)formamidine
title_full_unstemmed A monoclinic polymorph of N,N′-bis­(2,6-diisopropyl­phen­yl)formamidine
title_short A monoclinic polymorph of N,N′-bis­(2,6-diisopropyl­phen­yl)formamidine
title_sort monoclinic polymorph of n,n′-bis­(2,6-diisopropyl­phen­yl)formamidine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962078/
https://www.ncbi.nlm.nih.gov/pubmed/21203162
http://dx.doi.org/10.1107/S160053680802076X
work_keys_str_mv AT masudajasond amonoclinicpolymorphofnnbis26diisopropylphenylformamidine
AT masudajasond monoclinicpolymorphofnnbis26diisopropylphenylformamidine

Ejemplares similares