N′-(3,5-Di-tert-butyl-4-hydroxy­benzyl­idene)-2-hydroxy­benzohydrazide methanol solvate

The asymmetric unit of the title compound, C(22)H(28)N(2)O(3)·CH(4)O, consists of two independent Schiff base mol­ecules and two independent methanol solvent mol­ecules. In one Schiff base mol­ecule, the 2-hydr­oxy group forms an intra­molecular hydrogen bond with the amide O atom, whereas in the ot...

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Detalles Bibliográficos
Autores principales: Yehye, Wagee A., Ariffin, Azhar, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962083/
https://www.ncbi.nlm.nih.gov/pubmed/21203167
http://dx.doi.org/10.1107/S1600536808020746
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author Yehye, Wagee A.
Ariffin, Azhar
Ng, Seik Weng
author_facet Yehye, Wagee A.
Ariffin, Azhar
Ng, Seik Weng
author_sort Yehye, Wagee A.
collection PubMed
description The asymmetric unit of the title compound, C(22)H(28)N(2)O(3)·CH(4)O, consists of two independent Schiff base mol­ecules and two independent methanol solvent mol­ecules. In one Schiff base mol­ecule, the 2-hydr­oxy group forms an intra­molecular hydrogen bond with the amide O atom, whereas in the other Schiff base mol­ecule, the 2-hydr­oxy-substituted benzene ring is oriented so that the 2-hydr­oxy group serves as hydrogen-bond acceptor for the amide NH group. In the crystal structure, Schiff base mol­ecules inter­act with methanol solvent to furnish a hydrogen-bonded chain.
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spelling pubmed-29620832010-12-30 N′-(3,5-Di-tert-butyl-4-hydroxy­benzyl­idene)-2-hydroxy­benzohydrazide methanol solvate Yehye, Wagee A. Ariffin, Azhar Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(22)H(28)N(2)O(3)·CH(4)O, consists of two independent Schiff base mol­ecules and two independent methanol solvent mol­ecules. In one Schiff base mol­ecule, the 2-hydr­oxy group forms an intra­molecular hydrogen bond with the amide O atom, whereas in the other Schiff base mol­ecule, the 2-hydr­oxy-substituted benzene ring is oriented so that the 2-hydr­oxy group serves as hydrogen-bond acceptor for the amide NH group. In the crystal structure, Schiff base mol­ecules inter­act with methanol solvent to furnish a hydrogen-bonded chain. International Union of Crystallography 2008-07-09 /pmc/articles/PMC2962083/ /pubmed/21203167 http://dx.doi.org/10.1107/S1600536808020746 Text en © Yehye et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Yehye, Wagee A.
Ariffin, Azhar
Ng, Seik Weng
N′-(3,5-Di-tert-butyl-4-hydroxy­benzyl­idene)-2-hydroxy­benzohydrazide methanol solvate
title N′-(3,5-Di-tert-butyl-4-hydroxy­benzyl­idene)-2-hydroxy­benzohydrazide methanol solvate
title_full N′-(3,5-Di-tert-butyl-4-hydroxy­benzyl­idene)-2-hydroxy­benzohydrazide methanol solvate
title_fullStr N′-(3,5-Di-tert-butyl-4-hydroxy­benzyl­idene)-2-hydroxy­benzohydrazide methanol solvate
title_full_unstemmed N′-(3,5-Di-tert-butyl-4-hydroxy­benzyl­idene)-2-hydroxy­benzohydrazide methanol solvate
title_short N′-(3,5-Di-tert-butyl-4-hydroxy­benzyl­idene)-2-hydroxy­benzohydrazide methanol solvate
title_sort n′-(3,5-di-tert-butyl-4-hydroxy­benzyl­idene)-2-hydroxy­benzohydrazide methanol solvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962083/
https://www.ncbi.nlm.nih.gov/pubmed/21203167
http://dx.doi.org/10.1107/S1600536808020746
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AT ariffinazhar n35ditertbutyl4hydroxybenzylidene2hydroxybenzohydrazidemethanolsolvate
AT ngseikweng n35ditertbutyl4hydroxybenzylidene2hydroxybenzohydrazidemethanolsolvate

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