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1-Methyl-2-[(E)-2-(2-thienyl)ethenyl]quinolinium iodide
In the title compound, C(16)H(14)NS(+)·I(−), the cation has an E configuration about the C=C double bond of the ethylene unit. The dihedral angle between the thiophene ring and the quinolinium ring system is 11.67 (11)°. A weak C—H⋯S intramolecular interaction involving the thiophene ring gener...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962084/ https://www.ncbi.nlm.nih.gov/pubmed/21203168 http://dx.doi.org/10.1107/S1600536808020734 |
Sumario: | In the title compound, C(16)H(14)NS(+)·I(−), the cation has an E configuration about the C=C double bond of the ethylene unit. The dihedral angle between the thiophene ring and the quinolinium ring system is 11.67 (11)°. A weak C—H⋯S intramolecular interaction involving the thiophene ring generates an S(5) ring motif. In the crystal structure, the iodide ion, located between the cations arranged in an antiparallel manner, forms weak C—H⋯I interactions. The crystal structure is further stabilized by a π–π interaction between the thiophene and pyridine rings; the centroid–centroid distance is 3.6818 (13) Å. |
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