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1-Methyl-2-[(E)-2-(2-thienyl)ethenyl]quinolinium iodide
In the title compound, C(16)H(14)NS(+)·I(−), the cation has an E configuration about the C=C double bond of the ethylene unit. The dihedral angle between the thiophene ring and the quinolinium ring system is 11.67 (11)°. A weak C—H⋯S intramolecular interaction involving the thiophene ring gener...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962084/ https://www.ncbi.nlm.nih.gov/pubmed/21203168 http://dx.doi.org/10.1107/S1600536808020734 |
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author | Ruanwas, Pumsak Kobkeatthawin, Thawanrat Chantrapromma, Suchada Fun, Hoong-Kun Karalai, Chatchanok |
author_facet | Ruanwas, Pumsak Kobkeatthawin, Thawanrat Chantrapromma, Suchada Fun, Hoong-Kun Karalai, Chatchanok |
author_sort | Ruanwas, Pumsak |
collection | PubMed |
description | In the title compound, C(16)H(14)NS(+)·I(−), the cation has an E configuration about the C=C double bond of the ethylene unit. The dihedral angle between the thiophene ring and the quinolinium ring system is 11.67 (11)°. A weak C—H⋯S intramolecular interaction involving the thiophene ring generates an S(5) ring motif. In the crystal structure, the iodide ion, located between the cations arranged in an antiparallel manner, forms weak C—H⋯I interactions. The crystal structure is further stabilized by a π–π interaction between the thiophene and pyridine rings; the centroid–centroid distance is 3.6818 (13) Å. |
format | Text |
id | pubmed-2962084 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29620842010-12-30 1-Methyl-2-[(E)-2-(2-thienyl)ethenyl]quinolinium iodide Ruanwas, Pumsak Kobkeatthawin, Thawanrat Chantrapromma, Suchada Fun, Hoong-Kun Karalai, Chatchanok Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(16)H(14)NS(+)·I(−), the cation has an E configuration about the C=C double bond of the ethylene unit. The dihedral angle between the thiophene ring and the quinolinium ring system is 11.67 (11)°. A weak C—H⋯S intramolecular interaction involving the thiophene ring generates an S(5) ring motif. In the crystal structure, the iodide ion, located between the cations arranged in an antiparallel manner, forms weak C—H⋯I interactions. The crystal structure is further stabilized by a π–π interaction between the thiophene and pyridine rings; the centroid–centroid distance is 3.6818 (13) Å. International Union of Crystallography 2008-07-09 /pmc/articles/PMC2962084/ /pubmed/21203168 http://dx.doi.org/10.1107/S1600536808020734 Text en © Ruanwas et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Ruanwas, Pumsak Kobkeatthawin, Thawanrat Chantrapromma, Suchada Fun, Hoong-Kun Karalai, Chatchanok 1-Methyl-2-[(E)-2-(2-thienyl)ethenyl]quinolinium iodide |
title | 1-Methyl-2-[(E)-2-(2-thienyl)ethenyl]quinolinium iodide
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title_full | 1-Methyl-2-[(E)-2-(2-thienyl)ethenyl]quinolinium iodide
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title_fullStr | 1-Methyl-2-[(E)-2-(2-thienyl)ethenyl]quinolinium iodide
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title_full_unstemmed | 1-Methyl-2-[(E)-2-(2-thienyl)ethenyl]quinolinium iodide
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title_short | 1-Methyl-2-[(E)-2-(2-thienyl)ethenyl]quinolinium iodide
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title_sort | 1-methyl-2-[(e)-2-(2-thienyl)ethenyl]quinolinium iodide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962084/ https://www.ncbi.nlm.nih.gov/pubmed/21203168 http://dx.doi.org/10.1107/S1600536808020734 |
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