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1-Methyl-2-[(E)-2-(2-thien­yl)ethen­yl]quinolinium iodide

In the title compound, C(16)H(14)NS(+)·I(−), the cation has an E configuration about the C=C double bond of the ethyl­ene unit. The dihedral angle between the thio­phene ring and the quinolinium ring system is 11.67 (11)°. A weak C—H⋯S intra­molecular inter­action involving the thio­phene ring gener...

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Autores principales: Ruanwas, Pumsak, Kobkeatthawin, Thawanrat, Chantrapromma, Suchada, Fun, Hoong-Kun, Karalai, Chatchanok
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962084/
https://www.ncbi.nlm.nih.gov/pubmed/21203168
http://dx.doi.org/10.1107/S1600536808020734
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author Ruanwas, Pumsak
Kobkeatthawin, Thawanrat
Chantrapromma, Suchada
Fun, Hoong-Kun
Karalai, Chatchanok
author_facet Ruanwas, Pumsak
Kobkeatthawin, Thawanrat
Chantrapromma, Suchada
Fun, Hoong-Kun
Karalai, Chatchanok
author_sort Ruanwas, Pumsak
collection PubMed
description In the title compound, C(16)H(14)NS(+)·I(−), the cation has an E configuration about the C=C double bond of the ethyl­ene unit. The dihedral angle between the thio­phene ring and the quinolinium ring system is 11.67 (11)°. A weak C—H⋯S intra­molecular inter­action involving the thio­phene ring generates an S(5) ring motif. In the crystal structure, the iodide ion, located between the cations arranged in an anti­parallel manner, forms weak C—H⋯I inter­actions. The crystal structure is further stabilized by a π–π inter­action between the thio­phene and pyridine rings; the centroid–centroid distance is 3.6818 (13) Å.
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spelling pubmed-29620842010-12-30 1-Methyl-2-[(E)-2-(2-thien­yl)ethen­yl]quinolinium iodide Ruanwas, Pumsak Kobkeatthawin, Thawanrat Chantrapromma, Suchada Fun, Hoong-Kun Karalai, Chatchanok Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(16)H(14)NS(+)·I(−), the cation has an E configuration about the C=C double bond of the ethyl­ene unit. The dihedral angle between the thio­phene ring and the quinolinium ring system is 11.67 (11)°. A weak C—H⋯S intra­molecular inter­action involving the thio­phene ring generates an S(5) ring motif. In the crystal structure, the iodide ion, located between the cations arranged in an anti­parallel manner, forms weak C—H⋯I inter­actions. The crystal structure is further stabilized by a π–π inter­action between the thio­phene and pyridine rings; the centroid–centroid distance is 3.6818 (13) Å. International Union of Crystallography 2008-07-09 /pmc/articles/PMC2962084/ /pubmed/21203168 http://dx.doi.org/10.1107/S1600536808020734 Text en © Ruanwas et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ruanwas, Pumsak
Kobkeatthawin, Thawanrat
Chantrapromma, Suchada
Fun, Hoong-Kun
Karalai, Chatchanok
1-Methyl-2-[(E)-2-(2-thien­yl)ethen­yl]quinolinium iodide
title 1-Methyl-2-[(E)-2-(2-thien­yl)ethen­yl]quinolinium iodide
title_full 1-Methyl-2-[(E)-2-(2-thien­yl)ethen­yl]quinolinium iodide
title_fullStr 1-Methyl-2-[(E)-2-(2-thien­yl)ethen­yl]quinolinium iodide
title_full_unstemmed 1-Methyl-2-[(E)-2-(2-thien­yl)ethen­yl]quinolinium iodide
title_short 1-Methyl-2-[(E)-2-(2-thien­yl)ethen­yl]quinolinium iodide
title_sort 1-methyl-2-[(e)-2-(2-thien­yl)ethen­yl]quinolinium iodide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962084/
https://www.ncbi.nlm.nih.gov/pubmed/21203168
http://dx.doi.org/10.1107/S1600536808020734
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