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6-Azido-6-deoxy-α-l-galactose (6-azido-l-fucose) monohydrate
Although 6-azido-6-deoxy-l-galactose in aqueous solution is in equilibrium between the open-chain, furanose and pyranose forms, it crystallizes solely as 6-azido-6-deoxy-α-l-galactopyranose monohydrate, C(6)H(11)N(3)O(5)·H(2)O, with the six-membered ring adopting a chair conformation. The struc...
| Autores principales: | , , , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962088/ https://www.ncbi.nlm.nih.gov/pubmed/21203271 http://dx.doi.org/10.1107/S1600536808022563 |
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| author | Booth, K. Victoria Jenkinson, Sarah F. Rao, Devendar Simonisi, Tsuyosi Fleet, George W. J. Izumori, Ken Watkin, David J. |
| author_facet | Booth, K. Victoria Jenkinson, Sarah F. Rao, Devendar Simonisi, Tsuyosi Fleet, George W. J. Izumori, Ken Watkin, David J. |
| author_sort | Booth, K. Victoria |
| collection | PubMed |
| description | Although 6-azido-6-deoxy-l-galactose in aqueous solution is in equilibrium between the open-chain, furanose and pyranose forms, it crystallizes solely as 6-azido-6-deoxy-α-l-galactopyranose monohydrate, C(6)H(11)N(3)O(5)·H(2)O, with the six-membered ring adopting a chair conformation. The structure exists as hydrogen-bonded chains, with each molecule acting as a donor and acceptor of five hydrogen bonds. There are no unusual crystal packing features and the absolute configuration was determined from the use of 1-azido-1-deoxy-d-galactitol as the starting material. |
| format | Text |
| id | pubmed-2962088 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29620882010-12-30 6-Azido-6-deoxy-α-l-galactose (6-azido-l-fucose) monohydrate Booth, K. Victoria Jenkinson, Sarah F. Rao, Devendar Simonisi, Tsuyosi Fleet, George W. J. Izumori, Ken Watkin, David J. Acta Crystallogr Sect E Struct Rep Online Organic Papers Although 6-azido-6-deoxy-l-galactose in aqueous solution is in equilibrium between the open-chain, furanose and pyranose forms, it crystallizes solely as 6-azido-6-deoxy-α-l-galactopyranose monohydrate, C(6)H(11)N(3)O(5)·H(2)O, with the six-membered ring adopting a chair conformation. The structure exists as hydrogen-bonded chains, with each molecule acting as a donor and acceptor of five hydrogen bonds. There are no unusual crystal packing features and the absolute configuration was determined from the use of 1-azido-1-deoxy-d-galactitol as the starting material. International Union of Crystallography 2008-07-23 /pmc/articles/PMC2962088/ /pubmed/21203271 http://dx.doi.org/10.1107/S1600536808022563 Text en © Booth et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Booth, K. Victoria Jenkinson, Sarah F. Rao, Devendar Simonisi, Tsuyosi Fleet, George W. J. Izumori, Ken Watkin, David J. 6-Azido-6-deoxy-α-l-galactose (6-azido-l-fucose) monohydrate |
| title | 6-Azido-6-deoxy-α-l-galactose (6-azido-l-fucose) monohydrate |
| title_full | 6-Azido-6-deoxy-α-l-galactose (6-azido-l-fucose) monohydrate |
| title_fullStr | 6-Azido-6-deoxy-α-l-galactose (6-azido-l-fucose) monohydrate |
| title_full_unstemmed | 6-Azido-6-deoxy-α-l-galactose (6-azido-l-fucose) monohydrate |
| title_short | 6-Azido-6-deoxy-α-l-galactose (6-azido-l-fucose) monohydrate |
| title_sort | 6-azido-6-deoxy-α-l-galactose (6-azido-l-fucose) monohydrate |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962088/ https://www.ncbi.nlm.nih.gov/pubmed/21203271 http://dx.doi.org/10.1107/S1600536808022563 |
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