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Methyl 2-[(E)-(4-nitro­phen­yl)hydrazono]-3-oxobutyrate

The mol­ecule of the title compound, C(11)H(11)N(3)O(5), exists as the E isomer as it is stabilized by an intra­molecular hydrogen bond. Except for the methyl H atoms, all atoms lie in special positions on a mirror plane and form a large conjugated system; the methyl H atoms are disordered about the...

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Detalles Bibliográficos
Autores principales: Liu, Yong-Hong, Sun, Gui-You, Liu, Jian-Feng, Ye, Jun, Liu, Xiao-Lan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962099/
https://www.ncbi.nlm.nih.gov/pubmed/21203301
http://dx.doi.org/10.1107/S160053680802312X
Descripción
Sumario:The mol­ecule of the title compound, C(11)H(11)N(3)O(5), exists as the E isomer as it is stabilized by an intra­molecular hydrogen bond. Except for the methyl H atoms, all atoms lie in special positions on a mirror plane and form a large conjugated system; the methyl H atoms are disordered about the mirror plane. In the crystalline state, bifurcated intra- and inter­molecular N—H⋯O hydrogen bonds and four inter­molecular C—H⋯O hydrogen bonds link the mol­ecules into large perfectly planar sheets. Along the c axis, the N—N bond center approaches the phenyl-ring centroids of its neighbouring mol­ecules above and below to give π–π overlap (at a distance of ca 3.57 Å), thus fusing the mol­ecules into a three-dimensional framework.