Cargando…
N,N′-Bis(3-bromobenzylidene)ethane-1,2-diamine
The molecule of the title Schiff base compound, C(16)H(14)Br(2)N(2), lies across a crystallographic inversion centre. The C=N bond adopts a trans configuration. The imino group is coplanar with the benzene ring. Within the molecule, the planar units are parallel, but extend in opposite directions...
Autores principales: | , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962103/ https://www.ncbi.nlm.nih.gov/pubmed/21203185 http://dx.doi.org/10.1107/S1600536808021132 |
_version_ | 1782189140953006080 |
---|---|
author | Fun, Hoong-Kun Mirkhani, Valiollah Kia, Reza Vartooni, Akbar Rostami |
author_facet | Fun, Hoong-Kun Mirkhani, Valiollah Kia, Reza Vartooni, Akbar Rostami |
author_sort | Fun, Hoong-Kun |
collection | PubMed |
description | The molecule of the title Schiff base compound, C(16)H(14)Br(2)N(2), lies across a crystallographic inversion centre. The C=N bond adopts a trans configuration. The imino group is coplanar with the benzene ring. Within the molecule, the planar units are parallel, but extend in opposite directions from the dimethylene bridge. The interesting feature of the structure is the weak Br⋯Br interaction [3.7501 (2) Å] linking the molecules into chains along the c axis. These chains are stacked along the b axis. |
format | Text |
id | pubmed-2962103 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29621032010-12-30 N,N′-Bis(3-bromobenzylidene)ethane-1,2-diamine Fun, Hoong-Kun Mirkhani, Valiollah Kia, Reza Vartooni, Akbar Rostami Acta Crystallogr Sect E Struct Rep Online Organic Papers The molecule of the title Schiff base compound, C(16)H(14)Br(2)N(2), lies across a crystallographic inversion centre. The C=N bond adopts a trans configuration. The imino group is coplanar with the benzene ring. Within the molecule, the planar units are parallel, but extend in opposite directions from the dimethylene bridge. The interesting feature of the structure is the weak Br⋯Br interaction [3.7501 (2) Å] linking the molecules into chains along the c axis. These chains are stacked along the b axis. International Union of Crystallography 2008-07-12 /pmc/articles/PMC2962103/ /pubmed/21203185 http://dx.doi.org/10.1107/S1600536808021132 Text en © Fun et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Fun, Hoong-Kun Mirkhani, Valiollah Kia, Reza Vartooni, Akbar Rostami N,N′-Bis(3-bromobenzylidene)ethane-1,2-diamine |
title |
N,N′-Bis(3-bromobenzylidene)ethane-1,2-diamine |
title_full |
N,N′-Bis(3-bromobenzylidene)ethane-1,2-diamine |
title_fullStr |
N,N′-Bis(3-bromobenzylidene)ethane-1,2-diamine |
title_full_unstemmed |
N,N′-Bis(3-bromobenzylidene)ethane-1,2-diamine |
title_short |
N,N′-Bis(3-bromobenzylidene)ethane-1,2-diamine |
title_sort | n,n′-bis(3-bromobenzylidene)ethane-1,2-diamine |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962103/ https://www.ncbi.nlm.nih.gov/pubmed/21203185 http://dx.doi.org/10.1107/S1600536808021132 |
work_keys_str_mv | AT funhoongkun nnbis3bromobenzylideneethane12diamine AT mirkhanivaliollah nnbis3bromobenzylideneethane12diamine AT kiareza nnbis3bromobenzylideneethane12diamine AT vartooniakbarrostami nnbis3bromobenzylideneethane12diamine |