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Tetra-O-4-methylphenylsulfonylpentaerythritol
In the title molecule (systematic name: methanetetrayltetramethylene tetra-p-toluenesulfonate), C(33)H(36)O(12)S(4), the central C atom and the S atoms exhibit distorted tetrahedral configurations. The aromatic rings in opposite arms are nearly parallel to each other, with a dihedral angle of...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962105/ https://www.ncbi.nlm.nih.gov/pubmed/21203187 http://dx.doi.org/10.1107/S1600536808020643 |
Sumario: | In the title molecule (systematic name: methanetetrayltetramethylene tetra-p-toluenesulfonate), C(33)H(36)O(12)S(4), the central C atom and the S atoms exhibit distorted tetrahedral configurations. The aromatic rings in opposite arms are nearly parallel to each other, with a dihedral angle of 10.26 (8) or 3.45 (9)°. The molecules are linked into a two-dimensional network parallel to the bc plane by weak C—H⋯O hydrogen bonds, π–π [centroid–centroid distance = 3.5806 (12) Å] and S—O⋯π [O⋯centroid = 3.1455 (15) Å and S—O⋯centroid = 122.41 (7)°] intermolecular interactions. Intramolecular C—H⋯O hydrogen bonds are also present. |
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