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Tetra-O-4-methyl­phenyl­sulfonyl­penta­erythritol

In the title mol­ecule (systematic name: methane­tetra­yltetra­methyl­ene tetra-p-toluene­sulfonate), C(33)H(36)O(12)S(4), the central C atom and the S atoms exhibit distorted tetra­hedral configurations. The aromatic rings in opposite arms are nearly parallel to each other, with a dihedral angle of...

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Detalles Bibliográficos
Autores principales: Li, Shu-Xian, Zhu, Lin, Fun, Hoong-Kun, Chantrapromma, Suchada
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962105/
https://www.ncbi.nlm.nih.gov/pubmed/21203187
http://dx.doi.org/10.1107/S1600536808020643
Descripción
Sumario:In the title mol­ecule (systematic name: methane­tetra­yltetra­methyl­ene tetra-p-toluene­sulfonate), C(33)H(36)O(12)S(4), the central C atom and the S atoms exhibit distorted tetra­hedral configurations. The aromatic rings in opposite arms are nearly parallel to each other, with a dihedral angle of 10.26 (8) or 3.45 (9)°. The mol­ecules are linked into a two-dimensional network parallel to the bc plane by weak C—H⋯O hydrogen bonds, π–π [centroid–centroid distance = 3.5806 (12) Å] and S—O⋯π [O⋯centroid = 3.1455 (15) Å and S—O⋯centroid = 122.41 (7)°] inter­molecular inter­actions. Intramolecular C—H⋯O hydrogen bonds are also present.