Tetra-O-4-methyl­phenyl­sulfonyl­penta­erythritol

In the title mol­ecule (systematic name: methane­tetra­yltetra­methyl­ene tetra-p-toluene­sulfonate), C(33)H(36)O(12)S(4), the central C atom and the S atoms exhibit distorted tetra­hedral configurations. The aromatic rings in opposite arms are nearly parallel to each other, with a dihedral angle of...

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Detalles Bibliográficos
Autores principales: Li, Shu-Xian, Zhu, Lin, Fun, Hoong-Kun, Chantrapromma, Suchada
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962105/
https://www.ncbi.nlm.nih.gov/pubmed/21203187
http://dx.doi.org/10.1107/S1600536808020643
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author Li, Shu-Xian
Zhu, Lin
Fun, Hoong-Kun
Chantrapromma, Suchada
author_facet Li, Shu-Xian
Zhu, Lin
Fun, Hoong-Kun
Chantrapromma, Suchada
author_sort Li, Shu-Xian
collection PubMed
description In the title mol­ecule (systematic name: methane­tetra­yltetra­methyl­ene tetra-p-toluene­sulfonate), C(33)H(36)O(12)S(4), the central C atom and the S atoms exhibit distorted tetra­hedral configurations. The aromatic rings in opposite arms are nearly parallel to each other, with a dihedral angle of 10.26 (8) or 3.45 (9)°. The mol­ecules are linked into a two-dimensional network parallel to the bc plane by weak C—H⋯O hydrogen bonds, π–π [centroid–centroid distance = 3.5806 (12) Å] and S—O⋯π [O⋯centroid = 3.1455 (15) Å and S—O⋯centroid = 122.41 (7)°] inter­molecular inter­actions. Intramolecular C—H⋯O hydrogen bonds are also present.
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spelling pubmed-29621052010-12-30 Tetra-O-4-methyl­phenyl­sulfonyl­penta­erythritol Li, Shu-Xian Zhu, Lin Fun, Hoong-Kun Chantrapromma, Suchada Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule (systematic name: methane­tetra­yltetra­methyl­ene tetra-p-toluene­sulfonate), C(33)H(36)O(12)S(4), the central C atom and the S atoms exhibit distorted tetra­hedral configurations. The aromatic rings in opposite arms are nearly parallel to each other, with a dihedral angle of 10.26 (8) or 3.45 (9)°. The mol­ecules are linked into a two-dimensional network parallel to the bc plane by weak C—H⋯O hydrogen bonds, π–π [centroid–centroid distance = 3.5806 (12) Å] and S—O⋯π [O⋯centroid = 3.1455 (15) Å and S—O⋯centroid = 122.41 (7)°] inter­molecular inter­actions. Intramolecular C—H⋯O hydrogen bonds are also present. International Union of Crystallography 2008-07-12 /pmc/articles/PMC2962105/ /pubmed/21203187 http://dx.doi.org/10.1107/S1600536808020643 Text en © Li et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Li, Shu-Xian
Zhu, Lin
Fun, Hoong-Kun
Chantrapromma, Suchada
Tetra-O-4-methyl­phenyl­sulfonyl­penta­erythritol
title Tetra-O-4-methyl­phenyl­sulfonyl­penta­erythritol
title_full Tetra-O-4-methyl­phenyl­sulfonyl­penta­erythritol
title_fullStr Tetra-O-4-methyl­phenyl­sulfonyl­penta­erythritol
title_full_unstemmed Tetra-O-4-methyl­phenyl­sulfonyl­penta­erythritol
title_short Tetra-O-4-methyl­phenyl­sulfonyl­penta­erythritol
title_sort tetra-o-4-methyl­phenyl­sulfonyl­penta­erythritol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962105/
https://www.ncbi.nlm.nih.gov/pubmed/21203187
http://dx.doi.org/10.1107/S1600536808020643
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AT funhoongkun tetrao4methylphenylsulfonylpentaerythritol
AT chantraprommasuchada tetrao4methylphenylsulfonylpentaerythritol

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