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2-Methyl-3-phenyl­sulfinyl-1-benzofuran

The title compound, C(15)H(12)O(2)S, was prepared by the oxidation of 2-methyl-3-phenyl­sulfanyl-1-benzofuran with 3-chloro­peroxy­benzoic acid. The O atom and the phenyl group of the phenyl­sulfinyl substituent lie on opposite sides of the plane of the benzofuran system. The phenyl ring makes a dih...

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Detalles Bibliográficos
Autores principales: Choi, Hong Dae, Seo, Pil Ja, Son, Byeng Wha, Lee, Uk
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962107/
https://www.ncbi.nlm.nih.gov/pubmed/21203189
http://dx.doi.org/10.1107/S1600536808021107
Descripción
Sumario:The title compound, C(15)H(12)O(2)S, was prepared by the oxidation of 2-methyl-3-phenyl­sulfanyl-1-benzofuran with 3-chloro­peroxy­benzoic acid. The O atom and the phenyl group of the phenyl­sulfinyl substituent lie on opposite sides of the plane of the benzofuran system. The phenyl ring makes a dihedral angle of 78.76 (4)° with the benzofuran mean plane. The crystal structure is stabilized by π–π inter­actions between the furan and benzene rings of neighbouring mol­ecules [centroid–centroid distance = 4.017 (3) Å]. In addition, the crystal structure exhibits inter­molecular C—H⋯π and C—H⋯O inter­actions.