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2-Methyl-3-phenyl­sulfinyl-1-benzofuran

The title compound, C(15)H(12)O(2)S, was prepared by the oxidation of 2-methyl-3-phenyl­sulfanyl-1-benzofuran with 3-chloro­peroxy­benzoic acid. The O atom and the phenyl group of the phenyl­sulfinyl substituent lie on opposite sides of the plane of the benzofuran system. The phenyl ring makes a dih...

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Detalles Bibliográficos
Autores principales: Choi, Hong Dae, Seo, Pil Ja, Son, Byeng Wha, Lee, Uk
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962107/
https://www.ncbi.nlm.nih.gov/pubmed/21203189
http://dx.doi.org/10.1107/S1600536808021107
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author Choi, Hong Dae
Seo, Pil Ja
Son, Byeng Wha
Lee, Uk
author_facet Choi, Hong Dae
Seo, Pil Ja
Son, Byeng Wha
Lee, Uk
author_sort Choi, Hong Dae
collection PubMed
description The title compound, C(15)H(12)O(2)S, was prepared by the oxidation of 2-methyl-3-phenyl­sulfanyl-1-benzofuran with 3-chloro­peroxy­benzoic acid. The O atom and the phenyl group of the phenyl­sulfinyl substituent lie on opposite sides of the plane of the benzofuran system. The phenyl ring makes a dihedral angle of 78.76 (4)° with the benzofuran mean plane. The crystal structure is stabilized by π–π inter­actions between the furan and benzene rings of neighbouring mol­ecules [centroid–centroid distance = 4.017 (3) Å]. In addition, the crystal structure exhibits inter­molecular C—H⋯π and C—H⋯O inter­actions.
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spelling pubmed-29621072010-12-30 2-Methyl-3-phenyl­sulfinyl-1-benzofuran Choi, Hong Dae Seo, Pil Ja Son, Byeng Wha Lee, Uk Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(15)H(12)O(2)S, was prepared by the oxidation of 2-methyl-3-phenyl­sulfanyl-1-benzofuran with 3-chloro­peroxy­benzoic acid. The O atom and the phenyl group of the phenyl­sulfinyl substituent lie on opposite sides of the plane of the benzofuran system. The phenyl ring makes a dihedral angle of 78.76 (4)° with the benzofuran mean plane. The crystal structure is stabilized by π–π inter­actions between the furan and benzene rings of neighbouring mol­ecules [centroid–centroid distance = 4.017 (3) Å]. In addition, the crystal structure exhibits inter­molecular C—H⋯π and C—H⋯O inter­actions. International Union of Crystallography 2008-07-12 /pmc/articles/PMC2962107/ /pubmed/21203189 http://dx.doi.org/10.1107/S1600536808021107 Text en © Choi et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Choi, Hong Dae
Seo, Pil Ja
Son, Byeng Wha
Lee, Uk
2-Methyl-3-phenyl­sulfinyl-1-benzofuran
title 2-Methyl-3-phenyl­sulfinyl-1-benzofuran
title_full 2-Methyl-3-phenyl­sulfinyl-1-benzofuran
title_fullStr 2-Methyl-3-phenyl­sulfinyl-1-benzofuran
title_full_unstemmed 2-Methyl-3-phenyl­sulfinyl-1-benzofuran
title_short 2-Methyl-3-phenyl­sulfinyl-1-benzofuran
title_sort 2-methyl-3-phenyl­sulfinyl-1-benzofuran
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962107/
https://www.ncbi.nlm.nih.gov/pubmed/21203189
http://dx.doi.org/10.1107/S1600536808021107
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