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1-[2-(4-Fluorobenzyloxy)-2-phenylethyl]-1H-benzimidazole
The asymmetric unit of the title compound, C(22)H(19)FN(2)O, contains two independent molecules. The planar benzimidazole ring systems are oriented with respect to the phenyl/fluorobenzene rings at dihedral angles of 31.10 (4)/45.17 (5) and 45.52 (5)/68.63 (5)°, respectively, for the two molecul...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962126/ https://www.ncbi.nlm.nih.gov/pubmed/21203208 http://dx.doi.org/10.1107/S1600536808021326 |
Sumario: | The asymmetric unit of the title compound, C(22)H(19)FN(2)O, contains two independent molecules. The planar benzimidazole ring systems are oriented with respect to the phenyl/fluorobenzene rings at dihedral angles of 31.10 (4)/45.17 (5) and 45.52 (5)/68.63 (5)°, respectively, for the two molecules. In the crystal structure, intermolecular C—H⋯N and intermolecular C—H⋯N and C—H⋯F hydrogen bonds link the molecules into a three-dimensional network. There are C—H⋯π contacts between the benzimidazole and fluorobenzene rings and a π–π contact between the benzimidazole and phenyl ring systems [centroid–centroid distance = 4.575 (1) Å]. |
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