1-[2-(4-Fluoro­benz­yloxy)-2-phenyl­ethyl]-1H-benzimidazole

The asymmetric unit of the title compound, C(22)H(19)FN(2)O, contains two independent mol­ecules. The planar benzimidazole ring systems are oriented with respect to the phen­yl/fluoro­benzene rings at dihedral angles of 31.10 (4)/45.17 (5) and 45.52 (5)/68.63 (5)°, respectively, for the two mol­ecul...

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Detalles Bibliográficos
Autores principales: Özel Güven, Özden, Erdoğan, Taner, Coles, Simon J., Hökelek, Tuncer
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962126/
https://www.ncbi.nlm.nih.gov/pubmed/21203208
http://dx.doi.org/10.1107/S1600536808021326
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author Özel Güven, Özden
Erdoğan, Taner
Coles, Simon J.
Hökelek, Tuncer
author_facet Özel Güven, Özden
Erdoğan, Taner
Coles, Simon J.
Hökelek, Tuncer
author_sort Özel Güven, Özden
collection PubMed
description The asymmetric unit of the title compound, C(22)H(19)FN(2)O, contains two independent mol­ecules. The planar benzimidazole ring systems are oriented with respect to the phen­yl/fluoro­benzene rings at dihedral angles of 31.10 (4)/45.17 (5) and 45.52 (5)/68.63 (5)°, respectively, for the two mol­ecules. In the crystal structure, inter­molecular C—H⋯N and inter­molecular C—H⋯N and C—H⋯F hydrogen bonds link the mol­ecules into a three-dimensional network. There are C—H⋯π contacts between the benzimidazole and fluoro­benzene rings and a π–π contact between the benzimidazole and phenyl ring systems [centroid–centroid distance = 4.575 (1) Å].
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spelling pubmed-29621262010-12-30 1-[2-(4-Fluoro­benz­yloxy)-2-phenyl­ethyl]-1H-benzimidazole Özel Güven, Özden Erdoğan, Taner Coles, Simon J. Hökelek, Tuncer Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(22)H(19)FN(2)O, contains two independent mol­ecules. The planar benzimidazole ring systems are oriented with respect to the phen­yl/fluoro­benzene rings at dihedral angles of 31.10 (4)/45.17 (5) and 45.52 (5)/68.63 (5)°, respectively, for the two mol­ecules. In the crystal structure, inter­molecular C—H⋯N and inter­molecular C—H⋯N and C—H⋯F hydrogen bonds link the mol­ecules into a three-dimensional network. There are C—H⋯π contacts between the benzimidazole and fluoro­benzene rings and a π–π contact between the benzimidazole and phenyl ring systems [centroid–centroid distance = 4.575 (1) Å]. International Union of Crystallography 2008-07-16 /pmc/articles/PMC2962126/ /pubmed/21203208 http://dx.doi.org/10.1107/S1600536808021326 Text en © Özel Güven et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Özel Güven, Özden
Erdoğan, Taner
Coles, Simon J.
Hökelek, Tuncer
1-[2-(4-Fluoro­benz­yloxy)-2-phenyl­ethyl]-1H-benzimidazole
title 1-[2-(4-Fluoro­benz­yloxy)-2-phenyl­ethyl]-1H-benzimidazole
title_full 1-[2-(4-Fluoro­benz­yloxy)-2-phenyl­ethyl]-1H-benzimidazole
title_fullStr 1-[2-(4-Fluoro­benz­yloxy)-2-phenyl­ethyl]-1H-benzimidazole
title_full_unstemmed 1-[2-(4-Fluoro­benz­yloxy)-2-phenyl­ethyl]-1H-benzimidazole
title_short 1-[2-(4-Fluoro­benz­yloxy)-2-phenyl­ethyl]-1H-benzimidazole
title_sort 1-[2-(4-fluoro­benz­yloxy)-2-phenyl­ethyl]-1h-benzimidazole
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962126/
https://www.ncbi.nlm.nih.gov/pubmed/21203208
http://dx.doi.org/10.1107/S1600536808021326
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AT colessimonj 124fluorobenzyloxy2phenylethyl1hbenzimidazole
AT hokelektuncer 124fluorobenzyloxy2phenylethyl1hbenzimidazole

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