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4-[(E)-4-Bromobenzylideneamino]-3-methyl-1H-1,2,4-triazole-5(4H)-thione
In the title molecule, C(10)H(9)BrN(4)S, the dihedral angle between the triazole and benzene rings is 12.32 (19)°. An intramolecular C—H⋯S hydrogen bond generates an S(6) ring motif. In the crystal packing, centrosymmetrically related molecules are linked into a dimer by N—H⋯S hydrogen bonds, and...
Autores principales: | , , , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962136/ https://www.ncbi.nlm.nih.gov/pubmed/21203218 http://dx.doi.org/10.1107/S1600536808021636 |
Sumario: | In the title molecule, C(10)H(9)BrN(4)S, the dihedral angle between the triazole and benzene rings is 12.32 (19)°. An intramolecular C—H⋯S hydrogen bond generates an S(6) ring motif. In the crystal packing, centrosymmetrically related molecules are linked into a dimer by N—H⋯S hydrogen bonds, and the dimers are linked into a chain running along [1[Image: see text]1] by Br⋯N short contacts [3.187 (3) Å]. The crystal packing is further strengthened by π–π interactions involving the triazole ring [centroid–centroid distance = 3.322 (2) Å]. |
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