(3R,4S,5S)-4-Hydr­oxy-3-methyl-5-[(2S,3R)-3-methyl­pent-4-en-2-yl]tetra­hydro­furan-2-one

The title compound, C(11)H(18)O(3), was synthesized to prove the relative configuration of the corresponding acyclic C1—C8 stereopentade. It crystallizes with two mol­ecules in the asymmetric unit, which show only slight differences. The mol­ecules are linked via O—H⋯O hydrogen bonds, resulting in t...

Descripción completa

Detalles Bibliográficos
Autores principales: Becker, Annika, Schürmann, Markus, Preut, Hans, Hiersemann, Martin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962143/
https://www.ncbi.nlm.nih.gov/pubmed/21203225
http://dx.doi.org/10.1107/S1600536808021181
_version_ 1782189150402772992
author Becker, Annika
Schürmann, Markus
Preut, Hans
Hiersemann, Martin
author_facet Becker, Annika
Schürmann, Markus
Preut, Hans
Hiersemann, Martin
author_sort Becker, Annika
collection PubMed
description The title compound, C(11)H(18)O(3), was synthesized to prove the relative configuration of the corresponding acyclic C1—C8 stereopentade. It crystallizes with two mol­ecules in the asymmetric unit, which show only slight differences. The mol­ecules are linked via O—H⋯O hydrogen bonds, resulting in two crystallographically independent chains of mol­ecules propagating in the a-axis direction. The absolute configuration was known from the synthesis.
format Text
id pubmed-2962143
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29621432010-12-30 (3R,4S,5S)-4-Hydr­oxy-3-methyl-5-[(2S,3R)-3-methyl­pent-4-en-2-yl]tetra­hydro­furan-2-one Becker, Annika Schürmann, Markus Preut, Hans Hiersemann, Martin Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(11)H(18)O(3), was synthesized to prove the relative configuration of the corresponding acyclic C1—C8 stereopentade. It crystallizes with two mol­ecules in the asymmetric unit, which show only slight differences. The mol­ecules are linked via O—H⋯O hydrogen bonds, resulting in two crystallographically independent chains of mol­ecules propagating in the a-axis direction. The absolute configuration was known from the synthesis. International Union of Crystallography 2008-07-16 /pmc/articles/PMC2962143/ /pubmed/21203225 http://dx.doi.org/10.1107/S1600536808021181 Text en © Becker et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Becker, Annika
Schürmann, Markus
Preut, Hans
Hiersemann, Martin
(3R,4S,5S)-4-Hydr­oxy-3-methyl-5-[(2S,3R)-3-methyl­pent-4-en-2-yl]tetra­hydro­furan-2-one
title (3R,4S,5S)-4-Hydr­oxy-3-methyl-5-[(2S,3R)-3-methyl­pent-4-en-2-yl]tetra­hydro­furan-2-one
title_full (3R,4S,5S)-4-Hydr­oxy-3-methyl-5-[(2S,3R)-3-methyl­pent-4-en-2-yl]tetra­hydro­furan-2-one
title_fullStr (3R,4S,5S)-4-Hydr­oxy-3-methyl-5-[(2S,3R)-3-methyl­pent-4-en-2-yl]tetra­hydro­furan-2-one
title_full_unstemmed (3R,4S,5S)-4-Hydr­oxy-3-methyl-5-[(2S,3R)-3-methyl­pent-4-en-2-yl]tetra­hydro­furan-2-one
title_short (3R,4S,5S)-4-Hydr­oxy-3-methyl-5-[(2S,3R)-3-methyl­pent-4-en-2-yl]tetra­hydro­furan-2-one
title_sort (3r,4s,5s)-4-hydr­oxy-3-methyl-5-[(2s,3r)-3-methyl­pent-4-en-2-yl]tetra­hydro­furan-2-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962143/
https://www.ncbi.nlm.nih.gov/pubmed/21203225
http://dx.doi.org/10.1107/S1600536808021181
work_keys_str_mv AT beckerannika 3r4s5s4hydroxy3methyl52s3r3methylpent4en2yltetrahydrofuran2one
AT schurmannmarkus 3r4s5s4hydroxy3methyl52s3r3methylpent4en2yltetrahydrofuran2one
AT preuthans 3r4s5s4hydroxy3methyl52s3r3methylpent4en2yltetrahydrofuran2one
AT hiersemannmartin 3r4s5s4hydroxy3methyl52s3r3methylpent4en2yltetrahydrofuran2one

Ejemplares similares