2,2-Dichloro-N-(4-chloro­phenyl­sulfon­yl)­acetamide

In the crystal structure of the title compound (N4CPSDCAA), C(8)H(6)Cl(3)NO(3)S, the conformations of the N—H and C=O bonds in the SO(2)—NH—CO—C group are trans to each other, similar to those observed in 2,2-dichloro-N-(phenyl­sulfon­yl)­acetamide (NPSDCAA), 2,2-dichloro-N-(4-methyl­phenyl­sulfon­y...

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Autores principales: Gowda, B. Thimme, Foro, Sabine, Nirmala, P. G., Sowmya, B. P., Fuess, Hartmut
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962147/
https://www.ncbi.nlm.nih.gov/pubmed/21203229
http://dx.doi.org/10.1107/S1600536808021715
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author Gowda, B. Thimme
Foro, Sabine
Nirmala, P. G.
Sowmya, B. P.
Fuess, Hartmut
author_facet Gowda, B. Thimme
Foro, Sabine
Nirmala, P. G.
Sowmya, B. P.
Fuess, Hartmut
author_sort Gowda, B. Thimme
collection PubMed
description In the crystal structure of the title compound (N4CPSDCAA), C(8)H(6)Cl(3)NO(3)S, the conformations of the N—H and C=O bonds in the SO(2)—NH—CO—C group are trans to each other, similar to those observed in 2,2-dichloro-N-(phenyl­sulfon­yl)­acetamide (NPSDCAA), 2,2-dichloro-N-(4-methyl­phenyl­sulfon­yl)acetamide (N4MPSDCAA) and N-(4-chloro­phenyl­sulfon­yl)-2,2,2-trimethyl­acetamide (N4CPSTMAA), with similar bond parameters. The –SNHCOC– unit in N4CPSDCAA is essentially planar and makes a dihedral angle of 79.67 (5)° with the benzene ring, comparable to 79.75 (8)° in NPSDCAA, 81.02 (5)° in N4MPSDCAA and 82.2 (1)° in N4CPSTMAA. The mol­ecules in N4CPSDCAA are linked into layers parallel to the (001) plane by inter­molecular N—H⋯O hydrogen bonds.
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spelling pubmed-29621472010-12-30 2,2-Dichloro-N-(4-chloro­phenyl­sulfon­yl)­acetamide Gowda, B. Thimme Foro, Sabine Nirmala, P. G. Sowmya, B. P. Fuess, Hartmut Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title compound (N4CPSDCAA), C(8)H(6)Cl(3)NO(3)S, the conformations of the N—H and C=O bonds in the SO(2)—NH—CO—C group are trans to each other, similar to those observed in 2,2-dichloro-N-(phenyl­sulfon­yl)­acetamide (NPSDCAA), 2,2-dichloro-N-(4-methyl­phenyl­sulfon­yl)acetamide (N4MPSDCAA) and N-(4-chloro­phenyl­sulfon­yl)-2,2,2-trimethyl­acetamide (N4CPSTMAA), with similar bond parameters. The –SNHCOC– unit in N4CPSDCAA is essentially planar and makes a dihedral angle of 79.67 (5)° with the benzene ring, comparable to 79.75 (8)° in NPSDCAA, 81.02 (5)° in N4MPSDCAA and 82.2 (1)° in N4CPSTMAA. The mol­ecules in N4CPSDCAA are linked into layers parallel to the (001) plane by inter­molecular N—H⋯O hydrogen bonds. International Union of Crystallography 2008-07-19 /pmc/articles/PMC2962147/ /pubmed/21203229 http://dx.doi.org/10.1107/S1600536808021715 Text en © Gowda et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gowda, B. Thimme
Foro, Sabine
Nirmala, P. G.
Sowmya, B. P.
Fuess, Hartmut
2,2-Dichloro-N-(4-chloro­phenyl­sulfon­yl)­acetamide
title 2,2-Dichloro-N-(4-chloro­phenyl­sulfon­yl)­acetamide
title_full 2,2-Dichloro-N-(4-chloro­phenyl­sulfon­yl)­acetamide
title_fullStr 2,2-Dichloro-N-(4-chloro­phenyl­sulfon­yl)­acetamide
title_full_unstemmed 2,2-Dichloro-N-(4-chloro­phenyl­sulfon­yl)­acetamide
title_short 2,2-Dichloro-N-(4-chloro­phenyl­sulfon­yl)­acetamide
title_sort 2,2-dichloro-n-(4-chloro­phenyl­sulfon­yl)­acetamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962147/
https://www.ncbi.nlm.nih.gov/pubmed/21203229
http://dx.doi.org/10.1107/S1600536808021715
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AT sowmyabp 22dichloron4chlorophenylsulfonylacetamide
AT fuesshartmut 22dichloron4chlorophenylsulfonylacetamide

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