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2,2′-Dichloro-1,1′-[(propane-1,3-diyldioxy)bis(nitrilomethylidyne)]dibenzene
The title compound, C(17)H(16)Cl(2)N(2)O(2), assumes a V-shape configuration with a dihedral angle between the two halves of the molecule of 79.60 (4)°. The asymmetric unit comprises one half-molecule with a crystallographic twofold rotation axis passing through the central C atom. There are weak...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962157/ https://www.ncbi.nlm.nih.gov/pubmed/21203237 http://dx.doi.org/10.1107/S1600536808021739 |
Sumario: | The title compound, C(17)H(16)Cl(2)N(2)O(2), assumes a V-shape configuration with a dihedral angle between the two halves of the molecule of 79.60 (4)°. The asymmetric unit comprises one half-molecule with a crystallographic twofold rotation axis passing through the central C atom. There are weak intermolecular π–π stacking interactions between neighbouring benzene rings with intermolecular plane-to-plane distances of 3.277 (6) and 3.465 (5) Å along the a and c axes, respectively. In the crystal structure, weak intermolecular C—H⋯O bonds link each molecule to four others to form an infinite three-dimensional network. |
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