2,2′-Dichloro-1,1′-[(propane-1,3-diyldi­oxy)bis­(nitrilo­methyl­idyne)]dibenzene

The title compound, C(17)H(16)Cl(2)N(2)O(2), assumes a V-shape configuration with a dihedral angle between the two halves of the mol­ecule of 79.60 (4)°. The asymmetric unit comprises one half-mol­ecule with a crystallographic twofold rotation axis passing through the central C atom. There are weak...

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Detalles Bibliográficos
Autores principales: He, Xue-Ni, Dong, Wen-Kui, Bai, Wen-Juan, Yan, Hai-Bo, Lv, Zhong-Wu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962157/
https://www.ncbi.nlm.nih.gov/pubmed/21203237
http://dx.doi.org/10.1107/S1600536808021739
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author He, Xue-Ni
Dong, Wen-Kui
Bai, Wen-Juan
Yan, Hai-Bo
Lv, Zhong-Wu
author_facet He, Xue-Ni
Dong, Wen-Kui
Bai, Wen-Juan
Yan, Hai-Bo
Lv, Zhong-Wu
author_sort He, Xue-Ni
collection PubMed
description The title compound, C(17)H(16)Cl(2)N(2)O(2), assumes a V-shape configuration with a dihedral angle between the two halves of the mol­ecule of 79.60 (4)°. The asymmetric unit comprises one half-mol­ecule with a crystallographic twofold rotation axis passing through the central C atom. There are weak inter­molecular π–π stacking inter­actions between neighbouring benzene rings with inter­molecular plane-to-plane distances of 3.277 (6) and 3.465 (5) Å along the a and c axes, respectively. In the crystal structure, weak inter­molecular C—H⋯O bonds link each mol­ecule to four others to form an infinite three-dimensional network.
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spelling pubmed-29621572010-12-30 2,2′-Dichloro-1,1′-[(propane-1,3-diyldi­oxy)bis­(nitrilo­methyl­idyne)]dibenzene He, Xue-Ni Dong, Wen-Kui Bai, Wen-Juan Yan, Hai-Bo Lv, Zhong-Wu Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(17)H(16)Cl(2)N(2)O(2), assumes a V-shape configuration with a dihedral angle between the two halves of the mol­ecule of 79.60 (4)°. The asymmetric unit comprises one half-mol­ecule with a crystallographic twofold rotation axis passing through the central C atom. There are weak inter­molecular π–π stacking inter­actions between neighbouring benzene rings with inter­molecular plane-to-plane distances of 3.277 (6) and 3.465 (5) Å along the a and c axes, respectively. In the crystal structure, weak inter­molecular C—H⋯O bonds link each mol­ecule to four others to form an infinite three-dimensional network. International Union of Crystallography 2008-07-19 /pmc/articles/PMC2962157/ /pubmed/21203237 http://dx.doi.org/10.1107/S1600536808021739 Text en © He et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
He, Xue-Ni
Dong, Wen-Kui
Bai, Wen-Juan
Yan, Hai-Bo
Lv, Zhong-Wu
2,2′-Dichloro-1,1′-[(propane-1,3-diyldi­oxy)bis­(nitrilo­methyl­idyne)]dibenzene
title 2,2′-Dichloro-1,1′-[(propane-1,3-diyldi­oxy)bis­(nitrilo­methyl­idyne)]dibenzene
title_full 2,2′-Dichloro-1,1′-[(propane-1,3-diyldi­oxy)bis­(nitrilo­methyl­idyne)]dibenzene
title_fullStr 2,2′-Dichloro-1,1′-[(propane-1,3-diyldi­oxy)bis­(nitrilo­methyl­idyne)]dibenzene
title_full_unstemmed 2,2′-Dichloro-1,1′-[(propane-1,3-diyldi­oxy)bis­(nitrilo­methyl­idyne)]dibenzene
title_short 2,2′-Dichloro-1,1′-[(propane-1,3-diyldi­oxy)bis­(nitrilo­methyl­idyne)]dibenzene
title_sort 2,2′-dichloro-1,1′-[(propane-1,3-diyldi­oxy)bis­(nitrilo­methyl­idyne)]dibenzene
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962157/
https://www.ncbi.nlm.nih.gov/pubmed/21203237
http://dx.doi.org/10.1107/S1600536808021739
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