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N-(Fluoren-9-ylmethoxy­carbon­yl)-l-isoleucine

In the crystal structure of the title compound [systematic name fluoren-9-ylmethyl N-(1-carb­oxy-2-methyl­butyl)carbamate], C(21)H(23)NO(4), the mol­ecular plane of the O=C—NH—C(α) unit is slightly pyramidalized. The N atom deviates from the basal plane by 0.2086 (12) Å. The O=C—N—C(α) torsion angle...

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Detalles Bibliográficos
Autores principales: Yamada, Kazuhiko, Hashizume, Daisuke, Shimizu, Tadashi, Deguchi, Kenzo
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962158/
https://www.ncbi.nlm.nih.gov/pubmed/21203238
http://dx.doi.org/10.1107/S1600536808021855
Descripción
Sumario:In the crystal structure of the title compound [systematic name fluoren-9-ylmethyl N-(1-carb­oxy-2-methyl­butyl)carbamate], C(21)H(23)NO(4), the mol­ecular plane of the O=C—NH—C(α) unit is slightly pyramidalized. The N atom deviates from the basal plane by 0.2086 (12) Å. The O=C—N—C(α) torsion angle is −17.2 (2)°, and the C—N and O=C bond lengths are 1.3675 (17) and 1.2122 (17) Å, respectively. Apparently the character of the sp (2) hybrids of the mol­ecular plane is, to some extent, reduced. The crystal structure exhibits two inter­molecular hydrogen bonds (O—H⋯O and N—H⋯O), in which the hydr­oxy O atom acts as a donor to the carbonyl group and an acceptor of the amide group, respectively.