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(S)-2-[(2-Ammoniophenyl)sulfanylmethyl]pyrrolidinium dibromide
In the title compound, C(11)H(18)N(2)S(2+)·2Br(−), the pyrrolidine ring displays a half-chair conformation, with the flap C atom lying 0.522 (5) Å out of the plane of the other four atoms. The methylene C atom, which connects the pyrrolidinium ring and the thioether group, is displaced from the pl...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962173/ https://www.ncbi.nlm.nih.gov/pubmed/21203253 http://dx.doi.org/10.1107/S1600536808021089 |
Sumario: | In the title compound, C(11)H(18)N(2)S(2+)·2Br(−), the pyrrolidine ring displays a half-chair conformation, with the flap C atom lying 0.522 (5) Å out of the plane of the other four atoms. The methylene C atom, which connects the pyrrolidinium ring and the thioether group, is displaced from the plane of four pyrrolidinium atoms by 0.690 (6) Å in the same direction as the flap C atom. The plane of four pyrrolidinium atoms is almost perpendicular to the benzene ring [dihedral angle = 75.02 (4)°]. The crystal structure is stabilized by hydrogen bonds between the N and Br atoms. |
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