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Ethyl 4-(tert-butyl­amino)-3-nitro­benzoate

In the title compound, C(13)H(18)N(2)O(4), intra­molecular N—H⋯O, N—H⋯N and C—H⋯O (× 3) hydrogen bonds generate S(6) and S(5) ring motifs. There are two crystallographically independent mol­ecules (A and B) in the asymmetric unit. The nitro group is coplanar with the benzene ring, with O—N—C—C torsi...

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Detalles Bibliográficos
Autores principales: Mohd. Maidin, Siti Marina, Abdul Rahim, Aisyah Saad, Osman, Hasnah, Kia, Reza, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962174/
https://www.ncbi.nlm.nih.gov/pubmed/21203254
http://dx.doi.org/10.1107/S160053680802206X
Descripción
Sumario:In the title compound, C(13)H(18)N(2)O(4), intra­molecular N—H⋯O, N—H⋯N and C—H⋯O (× 3) hydrogen bonds generate S(6) and S(5) ring motifs. There are two crystallographically independent mol­ecules (A and B) in the asymmetric unit. The nitro group is coplanar with the benzene ring, with O—N—C—C torsion angles of −0.33 (13) and 0.93 (14)° in mol­ecules A and B, respectively. In the crystal structure, neighbouring mol­ecules are linked together by inter­molecular C—H⋯O hydrogen bonds. In addition, the crystal structure is stabilized by π–π inter­actions with centroid–centroid distances ranging from 3.7853 (6) to 3.8625 (6) Å.