Tris(diisopropyl­ammonium) hydrogensulfate sulfate

The cations and anions of the title salt, 3C(6)H(16)N(+)·HSO(4) (−)·SO(4) (2−), are linked by N—H⋯O and O—H⋯O hydrogen bonds into a three-dimensional network. The hydrogensulfate ion, with a single S—O(H) bond of 1.563 (2) Å, forms a short O—H⋯O hydrogen bond [O⋯O = 2.609 (2) Å] to the sulfate ion....

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Detalles Bibliográficos
Autores principales: Mohammadnezhad, Gholamhossein Sh., Amini, Mostafa M., Khavasi, Hamid Reza, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962186/
https://www.ncbi.nlm.nih.gov/pubmed/21203267
http://dx.doi.org/10.1107/S160053680802237X
Descripción
Sumario:The cations and anions of the title salt, 3C(6)H(16)N(+)·HSO(4) (−)·SO(4) (2−), are linked by N—H⋯O and O—H⋯O hydrogen bonds into a three-dimensional network. The hydrogensulfate ion, with a single S—O(H) bond of 1.563 (2) Å, forms a short O—H⋯O hydrogen bond [O⋯O = 2.609 (2) Å] to the sulfate ion. The hydrogensulfate ion accepts two hydrogen bonds from two cations, whereas the sulfate ion, as an acceptor, binds to four cations. The sulfate ion is disordered approximately equally over two sites related by rotation around one of the O—S bonds.

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