Tris(diisopropyl­ammonium) hydrogensulfate sulfate

The cations and anions of the title salt, 3C(6)H(16)N(+)·HSO(4) (−)·SO(4) (2−), are linked by N—H⋯O and O—H⋯O hydrogen bonds into a three-dimensional network. The hydrogensulfate ion, with a single S—O(H) bond of 1.563 (2) Å, forms a short O—H⋯O hydrogen bond [O⋯O = 2.609 (2) Å] to the sulfate ion....

Descripción completa

Detalles Bibliográficos
Autores principales: Mohammadnezhad, Gholamhossein Sh., Amini, Mostafa M., Khavasi, Hamid Reza, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962186/
https://www.ncbi.nlm.nih.gov/pubmed/21203267
http://dx.doi.org/10.1107/S160053680802237X
_version_ 1782189160534114304
author Mohammadnezhad, Gholamhossein Sh.
Amini, Mostafa M.
Khavasi, Hamid Reza
Ng, Seik Weng
author_facet Mohammadnezhad, Gholamhossein Sh.
Amini, Mostafa M.
Khavasi, Hamid Reza
Ng, Seik Weng
author_sort Mohammadnezhad, Gholamhossein Sh.
collection PubMed
description The cations and anions of the title salt, 3C(6)H(16)N(+)·HSO(4) (−)·SO(4) (2−), are linked by N—H⋯O and O—H⋯O hydrogen bonds into a three-dimensional network. The hydrogensulfate ion, with a single S—O(H) bond of 1.563 (2) Å, forms a short O—H⋯O hydrogen bond [O⋯O = 2.609 (2) Å] to the sulfate ion. The hydrogensulfate ion accepts two hydrogen bonds from two cations, whereas the sulfate ion, as an acceptor, binds to four cations. The sulfate ion is disordered approximately equally over two sites related by rotation around one of the O—S bonds.
format Text
id pubmed-2962186
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29621862010-12-30 Tris(diisopropyl­ammonium) hydrogensulfate sulfate Mohammadnezhad, Gholamhossein Sh. Amini, Mostafa M. Khavasi, Hamid Reza Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Organic Papers The cations and anions of the title salt, 3C(6)H(16)N(+)·HSO(4) (−)·SO(4) (2−), are linked by N—H⋯O and O—H⋯O hydrogen bonds into a three-dimensional network. The hydrogensulfate ion, with a single S—O(H) bond of 1.563 (2) Å, forms a short O—H⋯O hydrogen bond [O⋯O = 2.609 (2) Å] to the sulfate ion. The hydrogensulfate ion accepts two hydrogen bonds from two cations, whereas the sulfate ion, as an acceptor, binds to four cations. The sulfate ion is disordered approximately equally over two sites related by rotation around one of the O—S bonds. International Union of Crystallography 2008-07-23 /pmc/articles/PMC2962186/ /pubmed/21203267 http://dx.doi.org/10.1107/S160053680802237X Text en © Mohammadnezhad et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Mohammadnezhad, Gholamhossein Sh.
Amini, Mostafa M.
Khavasi, Hamid Reza
Ng, Seik Weng
Tris(diisopropyl­ammonium) hydrogensulfate sulfate
title Tris(diisopropyl­ammonium) hydrogensulfate sulfate
title_full Tris(diisopropyl­ammonium) hydrogensulfate sulfate
title_fullStr Tris(diisopropyl­ammonium) hydrogensulfate sulfate
title_full_unstemmed Tris(diisopropyl­ammonium) hydrogensulfate sulfate
title_short Tris(diisopropyl­ammonium) hydrogensulfate sulfate
title_sort tris(diisopropyl­ammonium) hydrogensulfate sulfate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962186/
https://www.ncbi.nlm.nih.gov/pubmed/21203267
http://dx.doi.org/10.1107/S160053680802237X
work_keys_str_mv AT mohammadnezhadgholamhosseinsh trisdiisopropylammoniumhydrogensulfatesulfate
AT aminimostafam trisdiisopropylammoniumhydrogensulfatesulfate
AT khavasihamidreza trisdiisopropylammoniumhydrogensulfatesulfate
AT ngseikweng trisdiisopropylammoniumhydrogensulfatesulfate

Ejemplares similares